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Preparation of Enantioenriched gamma-Substituted Lactones via Asymmetric Transfer Hydrogenation of beta-Azidocyclopropane Carboxylates Using the Ru-TsDPEN Complex
Su, Y; Tu, YQ(涂永强); Gu, PM; Tu, YQ (reprint author), Lanzhou Univ, Dept Chem, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China.
Indexed BySCIE ; PubMed ; MEDLINE ; BIOSIS
2014-08-14
Source PublicationORGANIC LETTERS
Volume16Issue:16Pages:4204-4207
PublisherAMER CHEMICAL SOC
Publication PlaceWASHINGTON
AbstractThe asymmetric transfer hydrogenation of racemic beta-azidocyclopropane carboxylates has been explored. Ru-TsDPEN B is found to be a good catalyst for the formation of enantioenriched gamma-lactones through a four-step sequence of azide reduction/cyclopropane ring cleavage/ketone transfer hydrogenation/lactonization, and the enantiomeric excess of the lactones was up to 94%.
Department[Su, Yan;
Tu, Yong-Qiang] Lanzhou Univ, Dept Chem, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China;
[Su, Yan;
Gu, Peiming] Ningxia Univ, State Key Lab Cultivat Base Nat Gas Convers, Key Lab Energy Sources & Engn, Yinchuan 750021, Peoples R China;
[Su, Yan;
Gu, Peiming] Ningxia Univ, Dept Chem, Yinchuan 750021, Peoples R China
Subject AreaChemistry
Project NumberNational Natural Science Foundation of China [21262024] ; Program for New Century Excellent Talents in University [NCET-13-0874] ; Scientific Research Foundation for Returned Scholars (Ministry of Education of China)
Funding Project国家自然科学基金项目 ; 新世纪优秀人才支持计划
Funding OrganizationNSFC ; MOE
DOI10.1021/ol501895k
ISSN1523-7060
SubtypeArticle
Language英语
WOS IDWOS:000340517200038
PMID 25083937
BIOSIS IDBIOSIS:PREV201400658344
First Inst
Citation statistics
Cited Times:16[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.lzu.edu.cn/handle/262010/103051
Collection化学化工学院
Corresponding AuthorTu, YQ (reprint author), Lanzhou Univ, Dept Chem, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China.
Recommended Citation
GB/T 7714
Su, Y,Tu, YQ,Gu, PM,et al. Preparation of Enantioenriched gamma-Substituted Lactones via Asymmetric Transfer Hydrogenation of beta-Azidocyclopropane Carboxylates Using the Ru-TsDPEN Complex[J]. ORGANIC LETTERS,2014,16(16):4204-4207.
APA Su, Y,Tu, YQ,Gu, PM,&Tu, YQ .(2014).Preparation of Enantioenriched gamma-Substituted Lactones via Asymmetric Transfer Hydrogenation of beta-Azidocyclopropane Carboxylates Using the Ru-TsDPEN Complex.ORGANIC LETTERS,16(16),4204-4207.
MLA Su, Y,et al."Preparation of Enantioenriched gamma-Substituted Lactones via Asymmetric Transfer Hydrogenation of beta-Azidocyclopropane Carboxylates Using the Ru-TsDPEN Complex".ORGANIC LETTERS 16.16(2014):4204-4207.
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