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题名: Zn-II, Ni-II, and Mn-II Complexes Supported by N-Hydroxy-pyridine-2-carboxamidine: Syntheses, Structures, and Luminescent and Magnetic Properties
作者: Liu, YL; Chen, YM; Gao, Q; Liu, W; Li, YH; Li, W
收录类别: SCIE
出版日期: 2014
刊名: CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
卷号: 33, 期号:8, 页码:1171-1183
期刊主办单位: 中国化学会 ; 中国科学院福建物质结构研究所
出版者: CHINESE JOURNAL STRUCTURAL CHEMISTRY
出版地: FUJIAN
英文摘要: The employment of N-hydroxy-pyridine-2-carboxamidine in the coordination chemistry of zinc(II), nickel(II) and manganese(II) under solvothermal conditions is reported. Four complexes of compositions, [Zn-2(O2CMe)(3){(py)C(NH2)NOH}(4)](OH) (1), [Zn-4(OH)(2){(py)C(NH2)-NO}(4)Cl-2]center dot 3MeCN (2), [Ni(SO4)(H2O) {(py)C(NH2)NOH}(2)]center dot H2O (3) and [Mn(SO4) {(py)C(NH2)-NOH}(2)](n) (4), have been synthesized by rationally choosing different metal salts and dexterously employing acetate and sulfate ions as the bridging groups. Luminescent properties for 2 suggested strong emission in the solid state at room temperature. Variable temperature (2.0 similar to 300 K) magnetic studies for the linear chain complex 4 indicate weak antiferromagnetic Mn(II)center dot center dot center dot Mn(II) exchange interactions.
关键词: solvothermal ; N-hydroxy-pyridine-2-carboxamidine ; luminescence ; magnetic property
作者部门: [Liu Yong-Lu ; Chen Yan-Mei ; Gao Qian ; Liu Wei ; Li Ya-Hong] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China ; [Chen Yan-Mei ; Li Wu] Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China ; [Li Ya-Hong] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
通讯作者: Li, YH (reprint author), Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China.
学科分类: Chemistry; Crystallography
文章类型: Article
所属项目编号: NNSFC [21272167, 21201127] ; Graduate Education Innovation Project in Jiangsu Province [CXZZ12_0808, CXLX12_0784] ; KLSLRC [KLSLRC-KF-13-HX-1] ; Priority Academic Program Development of Jiangsu Higher Education Institution
所属项目名称: 国家自然科学基金项目
项目资助者: NSFC
语种: 英语
ISSN号: 0254-5861
WOS记录号: WOS:000341071000011
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内容类型: 期刊论文
URI标识: http://ir.lzu.edu.cn/handle/262010/103217
Appears in Collections:化学化工学院_期刊论文

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Recommended Citation:
Liu, YL,Chen, YM,Gao, Q,et al. Zn-II, Ni-II, and Mn-II Complexes Supported by N-Hydroxy-pyridine-2-carboxamidine: Syntheses, Structures, and Luminescent and Magnetic Properties[J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,2014,33(8):1171-1183.
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