兰州大学机构库 >化学化工学院
Zn-II, Ni-II, and Mn-II Complexes Supported by N-Hydroxy-pyridine-2-carboxamidine: Syntheses, Structures, and Luminescent and Magnetic Properties
Liu, YL; Chen, YM; Gao, Q; Liu, W; Li, YH; Li, W; Li, YH (reprint author), Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China.
收录类别SCIE
2014
发表期刊CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
卷号33期号:8页码:1171-1183
期刊主办单位中国化学会 ; 中国科学院福建物质结构研究所
出版者CHINESE JOURNAL STRUCTURAL CHEMISTRY
出版地FUJIAN
摘要The employment of N-hydroxy-pyridine-2-carboxamidine in the coordination chemistry of zinc(II), nickel(II) and manganese(II) under solvothermal conditions is reported. Four complexes of compositions, [Zn-2(O2CMe)(3){(py)C(NH2)NOH}(4)](OH) (1), [Zn-4(OH)(2){(py)C(NH2)-NO}(4)Cl-2]center dot 3MeCN (2), [Ni(SO4)(H2O) {(py)C(NH2)NOH}(2)]center dot H2O (3) and [Mn(SO4) {(py)C(NH2)-NOH}(2)](n) (4), have been synthesized by rationally choosing different metal salts and dexterously employing acetate and sulfate ions as the bridging groups. Luminescent properties for 2 suggested strong emission in the solid state at room temperature. Variable temperature (2.0 similar to 300 K) magnetic studies for the linear chain complex 4 indicate weak antiferromagnetic Mn(II)center dot center dot center dot Mn(II) exchange interactions.
关键词solvothermal N-hydroxy-pyridine-2-carboxamidine luminescence magnetic property
作者部门[Liu Yong-Lu;
Chen Yan-Mei;
Gao Qian;
Liu Wei;
Li Ya-Hong] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China;
[Chen Yan-Mei;
Li Wu] Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China;
[Li Ya-Hong] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
学科领域Chemistry ; Crystallography
所属项目编号NNSFC [21272167, 21201127] ; Graduate Education Innovation Project in Jiangsu Province [CXZZ12_0808, CXLX12_0784] ; KLSLRC [KLSLRC-KF-13-HX-1] ; Priority Academic Program Development of Jiangsu Higher Education Institution
资助项目国家自然科学基金项目
项目资助者NSFC
ISSN0254-5861
文章类型Article
语种英语
WOS记录号WOS:000341071000011
第一机构
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文献类型期刊论文
条目标识符http://ir.lzu.edu.cn/handle/262010/103217
Collection化学化工学院
通讯作者Li, YH (reprint author), Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China.
Recommended Citation:
GB/T 7714
Liu, YL,Chen, YM,Gao, Q,et al. Zn-II, Ni-II, and Mn-II Complexes Supported by N-Hydroxy-pyridine-2-carboxamidine: Syntheses, Structures, and Luminescent and Magnetic Properties[J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,2014,33(8):1171-1183.
APA Liu, YL.,Chen, YM.,Gao, Q.,Liu, W.,Li, YH.,...&Li, YH .(2014).Zn-II, Ni-II, and Mn-II Complexes Supported by N-Hydroxy-pyridine-2-carboxamidine: Syntheses, Structures, and Luminescent and Magnetic Properties.CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,33(8),1171-1183.
MLA Liu, YL,et al."Zn-II, Ni-II, and Mn-II Complexes Supported by N-Hydroxy-pyridine-2-carboxamidine: Syntheses, Structures, and Luminescent and Magnetic Properties".CHINESE JOURNAL OF STRUCTURAL CHEMISTRY 33.8(2014):1171-1183.
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