兰州大学机构库 >化学化工学院
Nickel(II)-Catalyzed Asymmetric Propargyl and Allyl Claisen Rearrangements to Allenyl-and Allyl-Substituted beta-Ketoesters
Liu, YB; Hu, HP; Zheng, HF; Xia, Y; Liu, XH; Lin, LL; Feng, XM; Feng, XM (reprint author), Sichuan Univ, Coll Chem, Minist Educ, Key Lab Green Chem & Technol, Chengdu 610064, Peoples R China.
2014-10-20
发表期刊ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
ISSN1433-7851
卷号53期号:43页码:11579-11582
出版者WILEY
摘要Highly efficient catalytic asymmetric Claisen rearrangements of O-propargyl -ketoesters and O-allyl -ketoesters have been accomplished under mild reaction conditions. In the presence of the chiral N,N-dioxide/Ni-II complex, a wide range of allenyl/allyl-substituted all-carbon quaternary -ketoesters was obtained in generally good yield (up to 99%) and high diastereoselectivity (up to 99:1 d.r.) with excellent enantioselectivity (up to 99% ee).
出版地WEINHEIM
关键词allenic compounds asymmetric catalysis heterocycles nickel rearrangement
学科领域Chemistry
作者部门[Liu, Yangbin;
Hu, Haipeng;
Zheng, Haifeng;
Xia, Yong;
Liu, Xiaohua;
Lin, Lili;
Feng, Xiaoming] Sichuan Univ, Coll Chem, Minist Educ, Key Lab Green Chem & Technol, Chengdu 610064, Peoples R China;
[Feng, Xiaoming] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
DOI10.1002/anie.201404643
文章类型Article
收录类别SCIE ; EI ; PubMed
所属项目编号National Basic Research Program of China (973 Program) [2011CB808600] ; National Natural Science Foundation of China [21290182, 21321061, 21172151] ; Ministry of Education [20110181130014]
语种英语
资助项目国家自然科学基金项目 ; 国家重点基础研究发展计划以及国家重大科学研究计划(973计划) ; 高等学校博士学科点专项科研基金
项目资助者NSFC ; MOST ; MOE
WOS记录号WOS:000343870400032
EI记录号20144400133294
PM记录号25213462
第一机构
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文献类型期刊论文
条目标识符http://ir.lzu.edu.cn/handle/262010/103298
Collection化学化工学院
通讯作者Feng, XM (reprint author), Sichuan Univ, Coll Chem, Minist Educ, Key Lab Green Chem & Technol, Chengdu 610064, Peoples R China.
Recommended Citation:
GB/T 7714
Liu, YB,Hu, HP,Zheng, HF,et al. Nickel(II)-Catalyzed Asymmetric Propargyl and Allyl Claisen Rearrangements to Allenyl-and Allyl-Substituted beta-Ketoesters[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2014,53(43):11579-11582.
APA Liu, YB.,Hu, HP.,Zheng, HF.,Xia, Y.,Liu, XH.,...&Feng, XM .(2014).Nickel(II)-Catalyzed Asymmetric Propargyl and Allyl Claisen Rearrangements to Allenyl-and Allyl-Substituted beta-Ketoesters.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,53(43),11579-11582.
MLA Liu, YB,et al."Nickel(II)-Catalyzed Asymmetric Propargyl and Allyl Claisen Rearrangements to Allenyl-and Allyl-Substituted beta-Ketoesters".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 53.43(2014):11579-11582.
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