兰州大学机构库 >化学化工学院
Solution processable octa(aminophenyl)silsesquioxane covalently cross-linked sulfonated polyimides for proton exchange membranes
Gong, CL(宫琛亮); Liang, Y; Qi, ZG; Li, H; Wu, ZY; Zhang, ZY; Zhang, SJ; Zhang, XD; Li, YF(李彦锋); Gong, CL (reprint author), Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China.
收录类别SCIE ; EI
2015-02-15
发表期刊JOURNAL OF MEMBRANE SCIENCE
卷号476期号:476页码:364-372
出版者ELSEVIER
出版地AMSTERDAM
摘要In this work, a series of octa(aminophenyl)silsesquioxane(OAPS) covalently cross-linked sulfonated polyimides (SPIs) were fabricated for improving their mechanical and chemical stability, reducing fuel crossover and improving proton conductivity as proton exchange membranes. The content of OAPS cross-linkers was modified from 0.2 to 1.6 mol% to control the degree of cross-linking. The resulting OAPS cross linked membranes were solution processable and exhibited higher strength, superior thermal and chemical stabilities, and lower methanol permeability compared with the linear SPI membrane. Compared with Nafion 117, all of the cross linked membranes exhibited comparable proton conductivity from 20 to 80 degrees C and at 100% relative humidity. Moreover, when the content of OAPS was 0.4 mol%, the cross linked SPI exhibited the highest proton conductivity (0.111 S/cm). (C) 2014 Elsevier B.V. All rights reserved.
关键词Proton exchange membranes Cross linking Sulfonated polyimide POSS
作者部门[Gong, Chenliang;
Liang, Yu;
Qi, Zhigang;
Li, Hui;
Wu, Zhongying;
Zhang, Zeying;
Zhang, Shujiang;
Zhang, Xiangdong;
Li, Yanfeng] Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
学科领域Engineering ; Polymer Science
所属项目编号National Natural Science Foundation of China [21204033] ; Natural Science Foundation of Gansu Province [1208RJYA016] ; Fundamental Research Funds for Central Universities [lzujbky-2012-23, lzujbky-2013-26]
资助项目国家自然科学基金项目 ; 中央高校基本科研业务费专项资金 ; 甘肃省青年科技基金计划
项目资助者NSFC ; LZU ; GSSTD
DOI10.1016/j.memsci.2014.12.002
ISSN0376-7388
文章类型Article
语种英语
WOS记录号WOS:000349382600040
EI记录号20145100352064
第一机构
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文献类型期刊论文
条目标识符http://ir.lzu.edu.cn/handle/262010/107409
Collection化学化工学院
通讯作者Gong, CL (reprint author), Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China.
Recommended Citation:
GB/T 7714
Gong, CL,Liang, Y,Qi, ZG,et al. Solution processable octa(aminophenyl)silsesquioxane covalently cross-linked sulfonated polyimides for proton exchange membranes[J]. JOURNAL OF MEMBRANE SCIENCE,2015,476(476):364-372.
APA Gong, CL.,Liang, Y.,Qi, ZG.,Li, H.,Wu, ZY.,...&Gong, CL .(2015).Solution processable octa(aminophenyl)silsesquioxane covalently cross-linked sulfonated polyimides for proton exchange membranes.JOURNAL OF MEMBRANE SCIENCE,476(476),364-372.
MLA Gong, CL,et al."Solution processable octa(aminophenyl)silsesquioxane covalently cross-linked sulfonated polyimides for proton exchange membranes".JOURNAL OF MEMBRANE SCIENCE 476.476(2015):364-372.
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