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题名: Preparation of a series of aCTV-based covalent organic frameworks and substituent effects on their properties
作者: Zhen, JR; Ding, SY(丁三元); Liu, JM; Huang, ZT; Wang, W(王为); Zheng, QY
收录类别: SCIE
出版日期: 2016
刊名: CRYSTENGCOMM
卷号: 18, 期号:6, 页码:1039-1045
英文摘要: A series of amino substituted cyclotrianisylene (aCTV)-based covalent organic frameworks (COFs), aCTV-COF1 to aCTV-COF4, have been synthesized. These crystalline analogues showed permanent porosity with BET surface areas from 656 m(2) g(-1) to 1428 m(2) g(-1). With the introduction of methoxy groups and hydroxyl groups at the phenyl linker moieties in aCTV-COF3 and aCTV-COF4, their properties (such as color, gas adsorption, hydrolytic stability and so on) have been influenced to a great extent. The CO2 sorption of aCTV-COF4 has increased significantly, and the H-2 uptake of aCTV-COF3 is obviously higher than those of aCTV-COF1 and aCTV-COF2. Moreover, the introduction of the methoxy and hydroxyl groups has made aCTV-COF3 and aCTV-COF4 have better hydrolytic stability.
作者部门: [Zhen, Jingru ; Huang, Zhitang ; Zheng, Qiyu] Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China ; [Ding, Sanyuan ; Wang, Wei] Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China ; [Liu, Junmin] Sun Yat Sen Univ, Sch Chem & Chem Engn, KLGHEI Environm & Energy Chem, Guangzhou 510275, Guangdong, Peoples R China
通讯作者: Zheng, QY (reprint author), Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China. ; Wang, W (reprint author), Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China.
学科分类: Chemistry; Crystallography
文章类型: Article
所属项目编号: Major State Basic Research Development Program of China [2011CB932501, 2013CB834504]
所属项目名称: 国家重点基础研究发展计划以及国家重大科学研究计划(973计划)
项目资助者: MOST
语种: 英语
DOI: 10.1039/c5ce02332g
ISSN号: 1466-8033
WOS记录号: WOS:000369609800022
IR记录号: WOS:000369609800022
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内容类型: 期刊论文
URI标识: http://ir.lzu.edu.cn/handle/262010/179965
Appears in Collections:化学化工学院_期刊论文

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Recommended Citation:
Zhen, JR,Ding, SY,Liu, JM,et al. Preparation of a series of aCTV-based covalent organic frameworks and substituent effects on their properties[J]. CRYSTENGCOMM,2016,18(6):1039-1045.
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