化学化工学院机构知识库

Institutional Repository, College of Chemistry and Chemical Engineering

 

兰州大学机构库  > 化学化工学院  > 期刊论文
题名: Tandem C-H oxidation/cyclization/rearrangement and its application to asymmetric syntheses of (-)-brussonol and (-)-przewalskine E
作者: Jiao, ZW; Tu, YQ(涂永强); Zhang, Q; Liu, WX; Zhang, SY; Wang, SH(王少华); Zhang, FM(张辅民); Jiang, S
收录类别: SCIE ; MEDLINE ; BIOSIS
出版日期: 2015-06
刊名: NATURE COMMUNICATIONS
卷号: 6
英文摘要: Natural products are a vital source of lead compounds in drug discovery. Development of efficient tandem reactions to build useful compounds and apply them to the synthesis of natural products is not only a significant challenge but also an important goal for chemists. Here we describe a tandem C-H oxidation/cyclization/rearrangement of isochroman-derived allylic silylethers, promoted by DDQ and InCl3. This method allows the efficient construction of tricyclic benzoxa[3.2.1] octanes with a wide substrate scope. We employ this tandem reaction to achieve the asymmetric total syntheses of (-)-brussonol and (-)-przewalskine E.
作者部门: [Jiao, Zhi-Wei ; Tu, Yong-Qiang ; Zhang, Qing ; Liu, Wen-Xing ; Zhang, Shu-Yu ; Wang, Shao-Hua ; Zhang, Fu-Min ; Jiang, Sen] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China ; [Jiao, Zhi-Wei ; Tu, Yong-Qiang ; Zhang, Qing ; Liu, Wen-Xing ; Zhang, Shu-Yu ; Wang, Shao-Hua ; Zhang, Fu-Min ; Jiang, Sen] Lanzhou Univ, Coll Chem & Chem Engn, Lanzhou 730000, Peoples R China ; [Tu, Yong-Qiang] Collaborat Innovat Ctr Chem Sci & Engn, Tianjin 300071, Peoples R China
通讯作者: Tu, YQ (reprint author), Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China.
学科分类: Science & Technology - Other Topics
文章类型: Article
所属项目编号: NSFC [21202073, 21290180, 21272097, 21372104, 21472077] ; '111' Program of MOE ; Project of MOST [2012ZX 09201101-003] ; [lzujbky-2013-236]
所属项目名称: 国家自然科学基金项目 ; 国家科技重大专项 ; 高等学校学科创新引智计划(111计划) ; 中央高校基本科研业务费专项资金
项目资助者: NSFC ; MOST ; MOE ; SAFEA ; LZU
语种: 英语
DOI: 10.1038/ncomms8332
ISSN号: 2041-1723
WOS记录号: WOS:000357172100015
PM记录号: 26081438
BIOSIS记录号: BCI:BCI201500551735
IR记录号: WOS:000357172100015
第一机构:
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.lzu.edu.cn/handle/262010/180077
Appears in Collections:化学化工学院_期刊论文

Files in This Item:

There are no files associated with this item.


Recommended Citation:
Jiao, ZW,Tu, YQ,Zhang, Q,et al. Tandem C-H oxidation/cyclization/rearrangement and its application to asymmetric syntheses of (-)-brussonol and (-)-przewalskine E[J]. NATURE COMMUNICATIONS,2015,6.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Altmetrics Score
 
Google Scholar
Similar articles in Google Scholar
[Jiao, ZW]'s Articles
[Tu, YQ]'s Articles
[Zhang, Q]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[Jiao, ZW]‘s Articles
[Tu, YQ]‘s Articles
[Zhang, Q]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Email:
Passwd
验 证:
换一张
Have you forgotten your password? Log In
Copyright © 2007-2017  兰州大学 - Feedback
Powered by CSpace