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题名: Palladium-Catalyzed Radical Cascade lododifluoromethylation/Cyclization of 1,6-Enynes with Ethyl Difluoroiodoacetate
作者: Wang, YQ; He, YT; Zhang, LL; Wu, XX; Liu, XY(刘雪原); Liang, YM(梁永民)
收录类别: SCIE ; PubMed ; BIOSIS
出版日期: 2015-09-04
刊名: ORGANIC LETTERS
卷号: 17, 期号:17, 页码:4280-4283
出版者: AMER CHEMICAL SOC
出版地: WASHINGTON
英文摘要: A novel and convenient Pd-catalyzed radical cascade iododifluoromethylation/cyclization of 1,6-enynes with ethyl difluoroiodoacetate is demonstrated. The proposed transformation presents high stereoselectivity under mild and facile reaction conditions, thereby allowing an efficient access to a variety of iodine-containing difluoromethylated pyrrolidines. A possible radical pathway for the transformation is proposed on the basis of the results of control experiments and relevant literature reviews.
作者部门: [Wang, Yu-Qi ; He, Yu-Tao ; Zhang, Lu-Lu ; Wu, Xin-Xing ; Liu, Xue-Yuan ; Liang, Yong-Min] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
通讯作者: Liang, YM (reprint author), Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China.
学科分类: Chemistry
文章类型: Article
所属项目编号: National Science Foundation [NSF21272101, 21472074, 21472073] ; "111" Project [J1103307] ; Program for Changjiang Scholars and Innovative Research Team in University [IRT1138]
所属项目名称: 国家自然科学基金项目 ; 国家基础科学人才培养基金项目 ; 长江学者和创新团队发展计划
项目资助者: NSFC ; MOE
语种: 英语
DOI: 10.1021/acs.orglett.5b02068
ISSN号: 1523-7060
WOS记录号: WOS:000361087200040
PM记录号: 26284442
BIOSIS记录号: BCI:BCI201500740216
IR记录号: WOS:000361087200040
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内容类型: 期刊论文
URI标识: http://ir.lzu.edu.cn/handle/262010/180167
Appears in Collections:化学化工学院_期刊论文

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Recommended Citation:
Wang, YQ,He, YT,Zhang, LL,et al. Palladium-Catalyzed Radical Cascade lododifluoromethylation/Cyclization of 1,6-Enynes with Ethyl Difluoroiodoacetate[J]. ORGANIC LETTERS,2015,17(17):4280-4283.
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