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兰州大学机构库  > 化学化工学院  > 期刊论文
题名: Copper-Catalyzed Cascade Cyclization for the Synthesis of Trifluoromethyl-Substituted Spiro-2H-azirines from 1,6-Enynes
作者: He, YT; Wang, Q; Zhao, J; Wang, XZ; Qiu, YF; Yang, YC; Hu, JY; Liu, XY(刘雪原); Liang, YM(梁永民)
收录类别: SCIE
出版日期: 2015-10-12
刊名: ADVANCED SYNTHESIS & CATALYSIS
卷号: 357, 期号:14-15, 页码:3069-3075
英文摘要: A method for the synthesis of trifluoromethyl CF3-substituted spirocyclic compounds containing with a unique quaternary carbon center from readily available starting materials has been developed. The reaction provides a facile access to 2H-azirines via cascade cyclization. These compounds constitute a new class of functionalized synthetic intermediates, which can be used for the synthesis of various nitrogen-containing heterocycles and biologically active CF3-containing compounds.
关键词: 2H-azirines ; cascade cyclization ; copper enynes ; spirocyclic skeleton
作者部门: [He, Yu-Tao ; Wang, Qiang ; Zhao, Jiahui ; Wang, Xiao-Zhen ; Qiu, Yi-Feng ; Yang, Yu-Chen ; Hu, Jing-Yuan ; Liu, Xue-Yuan ; Liang, Yong-Min] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China ; [Liang, Yong-Min] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
通讯作者: Liang, YM (reprint author), Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China.
学科分类: Chemistry
文章类型: Article
所属项目编号: National Natural Science Foundation [NSF 21272101, 21472074, 21472073] ; Fundamental Research Funds for Central Universities [lzujbky-2014-243] ; "111" Project [J1103307] ; Program for Changjiang Scholars, innovative Research Team in University [IRT1138] ; Cuiying Student Innovation Fund of Lanzhou University [CYCXJJ-2015003]
所属项目名称: 国家自然科学基金项目 ; 国家基础科学人才培养基金项目 ; 长江学者和创新团队发展计划 ; 中央高校基本科研业务费专项资金
项目资助者: NSFC ; MOE ; LZU
语种: 英语
DOI: 10.1002/adsc.201500510
ISSN号: 1615-4150
WOS记录号: WOS:000363507400009
IR记录号: WOS:000363507400009
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内容类型: 期刊论文
URI标识: http://ir.lzu.edu.cn/handle/262010/180191
Appears in Collections:化学化工学院_期刊论文

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Recommended Citation:
He, YT,Wang, Q,Zhao, J,et al. Copper-Catalyzed Cascade Cyclization for the Synthesis of Trifluoromethyl-Substituted Spiro-2H-azirines from 1,6-Enynes[J]. ADVANCED SYNTHESIS & CATALYSIS,2015,357(14-15):3069-3075.
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