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兰州大学机构库  > 化学化工学院  > 期刊论文
题名: BF3 center dot OEt2-AgSCF3 Mediated Trifluoromethylthiolation/Cascade Cyclization of Propynols: Synthesis of 4-((Trifluoromethyl)thio)-2H-chromene and 4-((Trifluoromethyl)thio)-1,2-dihydroquinoline Derivatives
作者: Qiu, YF; Song, XR; Li, M; Zhu, XY; Wang, AQ; Yang, F; Han, YP; Zhang, HR; Jin, DP; Li, YX; Liang, YM(梁永民)
收录类别: SCIE ; PubMed ; BIOSIS
出版日期: 2016-04-01
刊名: ORGANIC LETTERS
卷号: 18, 期号:7, 页码:1514-1517
出版者: AMER CHEMICAL SOC
出版地: WASHINGTON
英文摘要: A BF3 center dot OEt2-AgSCF3 mediated direct trifluoromethylthiolation/cascade cyclization of propynols involving the SCF3 anion nucleophilic pathway is developed. This protocol also provides an opportunity to construct valuable trifluoromethylthio-substituted 2H-chromene and 1,2-dihydroquinoline systems with high efficiency under mild conditions. Additionally, the developed BF3 center dot OEt2-AgSCF3 reaction system could be scaled up to gram quantities in a satisfactory yield without inert gas protection.
作者部门: [Qiu, Yi-Feng ; Li, Ming ; Zhu, Xin-Yu ; Wang, An-Qi ; Han, Ya-Ping ; Zhang, Heng-Rui ; Jin, Dong-Po ; Li, Ying-Xiu ; Liang, Yong-Min] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China ; [Song, Xian-Rong] Jiangxi Sci Technol Normal Univ, Jiangxi Key Lab Organ Chem, Nanchang, Peoples R China ; [Yang, Fang] Northwest A&F Univ, Coll Sci, 3 Taicheng Rd, Yangling, Peoples R China
通讯作者: Liang, YM (reprint author), Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China.
学科分类: Chemistry
文章类型: Article
所属项目编号: National Science Foundation [NSF21272101, NSF21472073, NSF21472074, NSF21302076] ; Program for Changjiang Scholars and Innovative Research Team in University [IRT15R28]
所属项目名称: 国家自然科学基金项目 ; 长江学者和创新团队发展计划
项目资助者: NSFC ; MOE
语种: 英语
DOI: 10.1021/acs.orglett.6b00065
ISSN号: 1523-7060
WOS记录号: WOS:000373519600005
PM记录号: 26974231
BIOSIS记录号: BCI:BCI201600378796
IR记录号: WOS:000373519600005
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内容类型: 期刊论文
URI标识: http://ir.lzu.edu.cn/handle/262010/180395
Appears in Collections:化学化工学院_期刊论文

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Recommended Citation:
Qiu, YF,Song, XR,Li, M,et al. BF3 center dot OEt2-AgSCF3 Mediated Trifluoromethylthiolation/Cascade Cyclization of Propynols: Synthesis of 4-((Trifluoromethyl)thio)-2H-chromene and 4-((Trifluoromethyl)thio)-1,2-dihydroquinoline Derivatives[J]. ORGANIC LETTERS,2016,18(7):1514-1517.
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