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A high mass loading electrode based on ultrathin Co3S4 nanosheets for high performance supercapacitor
Alternative TitleA high mass loading electrode based on ultrathin Co3S4nanosheets for high performance supercapacitor
Xin, BB; Zhao, YQ(赵永青); Xu, CL(徐彩玲); Xu, CL (reprint author), Lanzhou Univ, Key Lab Nonferrous Met Chem & Resources Utilizat, State Key Lab Appl Organ Chem, Minist Educ,Coll Chem & Chem Engn,Lab Special Fun, Lanzhou 730000, Peoples R China.
Indexed BySCIE ; EI
2016-08
Source PublicationJOURNAL OF SOLID STATE ELECTROCHEMISTRY
Volume20Issue:8Pages:2197-2205
PublisherSPRINGER
Publication PlaceNEW YORK
AbstractThere is a growing need for the electrode with high mass loading of active materials, where both high energy and high power densities are required, in current and near-future applications of supercapacitor. Here, an ultrathin Co3S4 nanosheet decorated electrode (denoted as Co3S4/NF) with mass loading of 6 mg cm(-2) is successfully fabricated by using highly dispersive Co3O4 nanowires on Ni foam (NF) as template. The nanosheets contained lots of about 3 similar to 5 nm micropores benefiting for the electrochemical reaction and assembled into a three-dimensional, honeycomb-like network with 0.5 similar to 1 mu m mesopore structure for promoting specific surface area of electrode. The improved electrochemical performance was achieved, including an excellent cycliability of 10,000 cycles at 10 A g(-1) and large specific capacitances of 2415 and 1152 F g(-1) at 1 and 20 A g(-1), respectively. Impressively, the asymmetric supercapacitor assembled with the activated carbon (AC) and Co3S4/NF electrode exhibits a high energy density of 79 Wh kg(-1) at a power density of 151 W kg(-1), a high power density of 3000 W kg(-1) at energy density of 30 Wh kg(-1) and 73 % retention of the initial capacitance after 10,000 charge-discharge cycles at 2 A g(-1). More importantly, the formation process of the ultrathin Co3S4 nanosheets upon reaction time is investigated, which is benefited from the gradual infiltration of sulfide ions and the template function of ultrafine Co3O4 nanowires in the anion-exchange reaction.
KeywordSupercapacitors High mass loading Ultrathin nanosheets Co3S4 Superior cycling stability
Department[Xin, Binbin;
Zhao, Yongqing;
Xu, Cailing] Lanzhou Univ, Key Lab Nonferrous Met Chem & Resources Utilizat, State Key Lab Appl Organ Chem, Minist Educ,Coll Chem & Chem Engn,Lab Special Fun, Lanzhou 730000, Peoples R China
Subject AreaElectrochemistry
Project NumberNatural Science Foundation of China (NNSFC) [21503102] ; Fundamental Research Funds for the Central University [lzujbky-2014-189] ; Science and Technology Program of Gansu Province of China [145RJZA176] ; National College Students' Innovative Entrepreneurial Training Program of Lanzhou University [201510730096]
Funding Project国家自然科学基金项目 ; 中央高校基本科研业务费专项资金 ; 甘肃省自然科学基金计划
Funding OrganizationNSFC ; LZU ; GSSTD
DOI10.1007/s10008-016-3225-4
ISSN1432-8488
SubtypeArticle
Language英语
WOS IDWOS:000380120600011
EI ID20161902362344
IRIDWOS:000380120600011
First Inst
Citation statistics
Cited Times:8[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.lzu.edu.cn/handle/262010/180510
Collection化学化工学院
Corresponding AuthorXu, CL (reprint author), Lanzhou Univ, Key Lab Nonferrous Met Chem & Resources Utilizat, State Key Lab Appl Organ Chem, Minist Educ,Coll Chem & Chem Engn,Lab Special Fun, Lanzhou 730000, Peoples R China.
Recommended Citation
GB/T 7714
Xin, BB,Zhao, YQ,Xu, CL,et al. A high mass loading electrode based on ultrathin Co3S4 nanosheets for high performance supercapacitor[J]. JOURNAL OF SOLID STATE ELECTROCHEMISTRY,2016,20(8):2197-2205.
APA Xin, BB,Zhao, YQ,Xu, CL,&Xu, CL .(2016).A high mass loading electrode based on ultrathin Co3S4 nanosheets for high performance supercapacitor.JOURNAL OF SOLID STATE ELECTROCHEMISTRY,20(8),2197-2205.
MLA Xin, BB,et al."A high mass loading electrode based on ultrathin Co3S4 nanosheets for high performance supercapacitor".JOURNAL OF SOLID STATE ELECTROCHEMISTRY 20.8(2016):2197-2205.
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