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题名: A metal-free transformation of alkynes to carbonyls directed by remote OH group
作者: Chen, DQ; Guo, CH; Zhang, HR; Jin, DP; Li, XS; Gao, P; Wu, XX; Liu, XY(刘雪原); Liang, YM(梁永民)
收录类别: SCIE
出版日期: 2016-08-07
刊名: GREEN CHEMISTRY
卷号: 18, 期号:15, 页码:4176-4180
英文摘要: A remote OH group-directed metal-free transformation of alkynes to carbonyl compounds has been developed. Using only HOAc and EtOH solvent, this reaction elegantly converts alkynes into valuable ketones by remote hydroxyl group activation. Through comparison and isotope labeling experiments, it was confirmed that the process operates via a hydration reaction involving an acetic acid molecule, instead of a water molecule.
作者部门: [Chen, Dao-Qian ; Guo, Chun-Huan ; Zhang, Heng-Rui ; Jin, Dong-Po ; Li, Xue-Song ; Wu, Xin-Xing ; Liu, Xue-Yuan ; Liang, Yong-Min] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China ; [Gao, Pin] Xi An Jiao Tong Univ, Sch Sci, Dept Chem, Xian 710049, Peoples R China ; [Gao, Pin] Xi An Jiao Tong Univ, MOE Key Lab Nonequilibrium Synth & Modulat Conden, Xian 710049, Peoples R China
通讯作者: Liu, XY (reprint author), Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China.
学科分类: Chemistry; Science & Technology - Other Topics
文章类型: Article
所属项目编号: National Science Foundation [NSF21472074] ; "111" Project
所属项目名称: 国家自然科学基金项目
项目资助者: NSFC
语种: 英语
DOI: 10.1039/c6gc01141a
ISSN号: 1463-9262
WOS记录号: WOS:000381328300004
IR记录号: WOS:000381328300004
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内容类型: 期刊论文
URI标识: http://ir.lzu.edu.cn/handle/262010/180537
Appears in Collections:化学化工学院_期刊论文

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Recommended Citation:
Chen, DQ,Guo, CH,Zhang, HR,et al. A metal-free transformation of alkynes to carbonyls directed by remote OH group[J]. GREEN CHEMISTRY,2016,18(15):4176-4180.
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