兰州大学机构库 >化学化工学院
Cobaloxime-catalyzed hydration of terminal alkynes without acidic promoters
Hou, ST; Yang, HJ; Cheng, B; Zhai, HB; Li, Y; Li, Y (reprint author), Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China.; Li, Y (reprint author), Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Bioorgan & Nat Prod Chem, Shanghai 200032, Peoples R China.; Zhai, HB (reprint author), Peking Univ, Sch Chem Biol & Biotechnol, Lab Chem Genom, Shenzhen Grad Sch, Shenzhen 518055, Peoples R China.
收录类别SCIE
2017-06-28
发表期刊CHEMICAL COMMUNICATIONS
卷号53期号:51
出版者ROYAL SOC CHEMISTRY
出版地CAMBRIDGE
摘要Cobaloxime (Co(dmgBF(2))(2)center dot 2H(2)O), an inexpensive first-row transition-metal complex, catalyzed hydration of terminal alkynes gave the corresponding methyl ketones in good to excellent yields under neutral conditions (additional protic acids and silver salts are not required). A wide range of functional groups, such as allyl ether, benzyl ethers, carboxylic esters, imides, amides, nitro, and halogens, were tolerated. The mild reaction conditions together with the inexpensive feature and easy availability of the catalyst well address the current challenges in the field of alkyne hydration.
作者部门[Hou, Shengtai;
Yang, Hongjian;
Cheng, Bin;
Zhai, Hongbin;
Li, Yun] Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China;
[Li, Yun] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Bioorgan & Nat Prod Chem, Shanghai 200032, Peoples R China;
[Zhai, Hongbin] Peking Univ, Sch Chem Biol & Biotechnol, Lab Chem Genom, Shenzhen Grad Sch, Shenzhen 518055, Peoples R China
学科领域Chemistry
所属项目编号National Natural Science Foundation of China [21572089] ; Program for Changjiang Scholars and Innovative Research Team in University [PCSIRT: IRT_15R28] ; FRFCU [lzujbky-2016-52, lzujbky-2016-ct02]
资助项目国家自然科学基金项目 ; 长江学者和创新团队发展计划 ; 中央高校基本科研业务费专项资金
项目资助者NSFC ; MOE ; LZU
DOI10.1039/c7cc03919k
ISSN1359-7345
文章类型Article
语种英语
WOS记录号WOS:000404282900029
IR记录号WOS:000404282900029
第一机构
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文献类型期刊论文
条目标识符http://ir.lzu.edu.cn/handle/262010/190177
Collection化学化工学院
通讯作者Zhai, HB; Li, Y (reprint author), Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China.; Li, Y (reprint author), Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Bioorgan & Nat Prod Chem, Shanghai 200032, Peoples R China.; Zhai, HB (reprint author), Peking Univ, Sch Chem Biol & Biotechnol, Lab Chem Genom, Shenzhen Grad Sch, Shenzhen 518055, Peoples R China.
作者单位16CHEM
Recommended Citation:
GB/T 7714
Hou, ST,Yang, HJ,Cheng, B,et al. Cobaloxime-catalyzed hydration of terminal alkynes without acidic promoters[J]. CHEMICAL COMMUNICATIONS,2017,53(51).
APA Hou, ST.,Yang, HJ.,Cheng, B.,Zhai, HB.,Li, Y.,...&Zhai, HB .(2017).Cobaloxime-catalyzed hydration of terminal alkynes without acidic promoters.CHEMICAL COMMUNICATIONS,53(51).
MLA Hou, ST,et al."Cobaloxime-catalyzed hydration of terminal alkynes without acidic promoters".CHEMICAL COMMUNICATIONS 53.51(2017).
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