化学化工学院机构知识库

Institutional Repository, College of Chemistry and Chemical Engineering

 

兰州大学机构库  > 化学化工学院  > 期刊论文
题名: Ruthenium-catalyzed umpolung carboxylation of hydrazones with CO2
作者: Yan, SS; Zhu, L; Ye, JH; Zhang, Z; Huang, H; Zeng, HY; Li, CJ; Lan, Y; Yu, DG
收录类别: SCIE
出版日期: 2018-06-07
刊名: CHEMICAL SCIENCE
卷号: 9, 页码:4873-4878
出版者: ROYAL SOC CHEMISTRY
出版地: CAMBRIDGE
英文摘要: The first ruthenium-catalyzed umpolung carboxylation of hydrazones with CO2 to generate important aryl acetic acids is reported. Besides aldehyde hydrazones, a variety of ketone hydrazones, which have not been successfully applied in previous umpolung reactions with other reactive electrophiles, also show high reactivity and selectivity under mild conditions. Moreover, this operationally simple protocol features good functional group tolerance, is readily scalable, and offers easy derivation of important structures, including bioactive felbinac and adiphenine. Computational studies reveal that this umpolung reaction proceeds through the generation of a Ru-nitrenoid followed by concerted [4 + 2] cycloaddition with CO2.
作者部门: [Yan, Si-Shun ; Ye, Jian-Heng ; Zhang, Zhen ; Huang, He ; Yu, Da-Gang] Sichuan Univ, Coll Chem, Minist Educ, Key Lab Green Chem & Technol, 29 Wangjiang Rd, Chengdu 610064, Sichuan, Peoples R China ; [Zhu, Lei ; Lan, Yu] Chongqing Univ, Sch Chem & Chem Engn, Chongqing 400030, Peoples R China ; [Zeng, Huiying ; Li, Chao-Jun] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China ; [Li, Chao-Jun] McGill Univ, Dept Chem, 801 Sherbrooke St W, Quebec City, PQ H3A 0B8, Canada ; [Li, Chao-Jun] McGill Univ, FQRNT Ctr Green Chem & Catalysis, 801 Sherbrooke St W, Quebec City, PQ H3A 0B8, Canada ; [Yu, Da-Gang] Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China
通讯作者: Yu, DG (reprint author), Sichuan Univ, Coll Chem, Minist Educ, Key Lab Green Chem & Technol, 29 Wangjiang Rd, Chengdu 610064, Sichuan, Peoples R China. ; Lan, Y (reprint author), Chongqing Univ, Sch Chem & Chem Engn, Chongqing 400030, Peoples R China. ; Li, CJ (reprint author), Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China. ; Li, CJ (reprint author), McGill Univ, Dept Chem, 801 Sherbrooke St W, Quebec City, PQ H3A 0B8, Canada. ; Li, CJ (reprint author), McGill Univ, FQRNT Ctr Green Chem & Catalysis, 801 Sherbrooke St W, Quebec City, PQ H3A 0B8, Canada. ; Yu, DG (reprint author), Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China.
学科分类: Chemistry
文章类型: Article
所属项目编号: National Natural Science Foundation of China [21502124, 21772020, 21372266] ; "973" Project from MOST of China [2015CB856600] ; Recruitment Program of Global Experts ; Fundamental Research Funds for the Central Universities
所属项目名称: 国家自然科学基金项目 ; 国家重点基础研究发展计划以及国家重大科学研究计划(973计划)
项目资助者: NSFC ; MOST
语种: 英语
DOI: 10.1039/c8sc01299g
ISSN号: 2041-6520
WOS记录号: WOS:000434243300018
第一机构:
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.lzu.edu.cn/handle/262010/196907
Appears in Collections:化学化工学院_期刊论文

Files in This Item:

There are no files associated with this item.


Recommended Citation:
Yan, SS,Zhu, L,Ye, JH,et al. Ruthenium-catalyzed umpolung carboxylation of hydrazones with CO2[J]. CHEMICAL SCIENCE,2018,9:4873-4878.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Altmetrics Score
 
Google Scholar
Similar articles in Google Scholar
[Yan, SS]'s Articles
[Zhu, L]'s Articles
[Ye, JH]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[Yan, SS]‘s Articles
[Zhu, L]‘s Articles
[Ye, JH]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Email:
Passwd
验 证:
换一张
Have you forgotten your password? Log In
Copyright © 2007-2018  兰州大学 - Feedback
Powered by CSpace