兰州大学机构库 >化学化工学院
Ruthenium-catalyzed umpolung carboxylation of hydrazones with CO2
Yan, SS; Zhu, L; Ye, JH; Zhang, Z; Huang, H; Zeng, HY; Li, CJ; Lan, Y; Yu, DG; Yu, DG (reprint author), Sichuan Univ, Coll Chem, Minist Educ, Key Lab Green Chem & Technol, 29 Wangjiang Rd, Chengdu 610064, Sichuan, Peoples R China.; Lan, Y (reprint author), Chongqing Univ, Sch Chem & Chem Engn, Chongqing 400030, Peoples R China.; Li, CJ (reprint author), Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China.; Li, CJ (reprint author), McGill Univ, Dept Chem, 801 Sherbrooke St W, Quebec City, PQ H3A 0B8, Canada.; Li, CJ (reprint author), McGill Univ, FQRNT Ctr Green Chem & Catalysis, 801 Sherbrooke St W, Quebec City, PQ H3A 0B8, Canada.; Yu, DG (reprint author), Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China.
收录类别SCIE
2018-06-07
发表期刊CHEMICAL SCIENCE
卷号9页码:4873-4878
出版者ROYAL SOC CHEMISTRY
出版地CAMBRIDGE
摘要The first ruthenium-catalyzed umpolung carboxylation of hydrazones with CO2 to generate important aryl acetic acids is reported. Besides aldehyde hydrazones, a variety of ketone hydrazones, which have not been successfully applied in previous umpolung reactions with other reactive electrophiles, also show high reactivity and selectivity under mild conditions. Moreover, this operationally simple protocol features good functional group tolerance, is readily scalable, and offers easy derivation of important structures, including bioactive felbinac and adiphenine. Computational studies reveal that this umpolung reaction proceeds through the generation of a Ru-nitrenoid followed by concerted [4 + 2] cycloaddition with CO2.
作者部门
[Yan, Si-Shun;
Ye, Jian-Heng;
Zhang, Zhen;
Huang, He;
Yu, Da-Gang] Sichuan Univ, Coll Chem, Minist Educ, Key Lab Green Chem & Technol, 29 Wangjiang Rd, Chengdu 610064, Sichuan, Peoples R China;
[Zhu, Lei;
Lan, Yu] Chongqing Univ, Sch Chem & Chem Engn, Chongqing 400030, Peoples R China;
[Zeng, Huiying;
Li, Chao-Jun] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China;
[Li, Chao-Jun] McGill Univ, Dept Chem, 801 Sherbrooke St W, Quebec City, PQ H3A 0B8, Canada...更多
学科领域Chemistry
所属项目编号National Natural Science Foundation of China [21502124, 21772020, 21372266] ; "973" Project from MOST of China [2015CB856600] ; Recruitment Program of Global Experts ; Fundamental Research Funds for the Central Universities
资助项目国家自然科学基金项目 ; 国家重点基础研究发展计划以及国家重大科学研究计划(973计划)
项目资助者NSFC ; MOST
DOI10.1039/c8sc01299g
ISSN2041-6520
文章类型Article
语种英语
WOS记录号WOS:000434243300018
第一机构
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文献类型期刊论文
条目标识符http://ir.lzu.edu.cn/handle/262010/196907
Collection化学化工学院
通讯作者Yu, DG (reprint author), Sichuan Univ, Coll Chem, Minist Educ, Key Lab Green Chem & Technol, 29 Wangjiang Rd, Chengdu 610064, Sichuan, Peoples R China.; Lan, Y (reprint author), Chongqing Univ, Sch Chem & Chem Engn, Chongqing 400030, Peoples R China.; Li, CJ (reprint author), Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China.; Li, CJ (reprint author), McGill Univ, Dept Chem, 801 Sherbrooke St W, Quebec City, PQ H3A 0B8, Canada.; Li, CJ (reprint author), McGill Univ, FQRNT Ctr Green Chem & Catalysis, 801 Sherbrooke St W, Quebec City, PQ H3A 0B8, Canada.; Yu, DG (reprint author), Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China.
Recommended Citation:
GB/T 7714
Yan, SS,Zhu, L,Ye, JH,et al. Ruthenium-catalyzed umpolung carboxylation of hydrazones with CO2[J]. CHEMICAL SCIENCE,2018,9:4873-4878.
APA Yan, SS.,Zhu, L.,Ye, JH.,Zhang, Z.,Huang, H.,...&Yu, DG .(2018).Ruthenium-catalyzed umpolung carboxylation of hydrazones with CO2.CHEMICAL SCIENCE,9,4873-4878.
MLA Yan, SS,et al."Ruthenium-catalyzed umpolung carboxylation of hydrazones with CO2".CHEMICAL SCIENCE 9(2018):4873-4878.
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