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NH4HF2 as a Selective TBS-Removal Reagent for the Synthesis of Highly Functionalized Spiroketal via Tandem Deprotection/Spiroketalization Procedure
Lu, H; Zhang, FM(张辅民); Pan, JL; Chen, T; Li, YF(李彦锋); Zhang, FM (reprint author), Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China.
2014-01-17
发表期刊JOURNAL OF ORGANIC CHEMISTRY
ISSN0022-3263
卷号79期号:2
出版者AMER CHEMICAL SOC
摘要NH4HF2 has been used for the first time to selectively remove the TBS protecting groups from diol ketone precursors in the synthesis of highly functionalized spiroketals. This method allows the synthesis of [5,6], [6,6], and [6,7] spiroketal skeletons, as well as benzannulated spiroketal with retention of acid-sensitive groups. In this way, spiroketals can be synthesized with diverse substituent groups in the skeleton or on side chains. To demonstrate the utility of this methodology, the diverse transformations of highly functionalized spiroketal 3f were also investigated.
出版地WASHINGTON
学科领域Chemistry
作者部门[Zhang, Fu-Min] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China;
Lanzhou Univ, Dept Chem, Lanzhou 730000, Peoples R China
DOI10.1021/jo402167q
文章类型Article
收录类别SCIE ; PubMed ; MEDLINE ; BIOSIS
所属项目编号NSFC [21272097, 21290181] ; "111"Program ; PCSIRT of MOE [IRT1138]
语种英语
资助项目国家自然科学基金项目 ; 长江学者和创新团队发展计划
项目资助者NSFC [21272097, 21290181]; "111"Program; PCSIRT of MOE [IRT1138] ; NSFC ; MOE
WOS记录号WOS:000330099000009
PM记录号24328167
BIOSIS记录号BIOSIS:PREV201400192392
第一机构
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文献类型期刊论文
条目标识符http://ir.lzu.edu.cn/handle/262010/75420
Collection化学化工学院
通讯作者Zhang, FM (reprint author), Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China.
Recommended Citation:
GB/T 7714
Lu, H,Zhang, FM,Pan, JL,et al. NH4HF2 as a Selective TBS-Removal Reagent for the Synthesis of Highly Functionalized Spiroketal via Tandem Deprotection/Spiroketalization Procedure[J]. JOURNAL OF ORGANIC CHEMISTRY,2014,79(2).
APA Lu, H,Zhang, FM,Pan, JL,Chen, T,Li, YF,&Zhang, FM .(2014).NH4HF2 as a Selective TBS-Removal Reagent for the Synthesis of Highly Functionalized Spiroketal via Tandem Deprotection/Spiroketalization Procedure.JOURNAL OF ORGANIC CHEMISTRY,79(2).
MLA Lu, H,et al."NH4HF2 as a Selective TBS-Removal Reagent for the Synthesis of Highly Functionalized Spiroketal via Tandem Deprotection/Spiroketalization Procedure".JOURNAL OF ORGANIC CHEMISTRY 79.2(2014).
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