兰州大学机构库 >化学化工学院
Construction of Covalent Organic Framework for Catalysis: Pd/COF-LZU1 in Suzuki-Miyaura Coupling Reaction
Ding, SY(丁三元); Gao, J; Wang, Q; Zhang, Y; Song, WG; Su, CY; Wang, W(王为); Wang, W (reprint author), Lanzhou Univ, State Key Lab Appl Organ Chem, Coll Chem & Chem Engn, Lanzhou 730000, Gansu, Peoples R China.
Indexed BySCIE ; EI ; PubMed ; ESI
ESI NOTE2017-07-19;Highly Cited Papers
2011-12-14
Source PublicationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume133Issue:49
PublisherAMER CHEMICAL SOC
Publication PlaceWASHINGTON
AbstractCovalent organic frameworks (COFs) are crystalline porous solids with well-defined two- or three-dimensional molecular structures. Although the structural regularity provides this new type of porous material with high potentials in catalysis, no example has been presented so far. Herein, we report the first application of a new COF material, COF-LZU1, for highly efficient catalysis. The easily prepared imine-linked COF-LZU1 possesses a two-dimensional eclipsed layered-sheet structure, making its incorporation with metal ions feasible. Via a simple post-treatment, a Pd(II)-containing COF, Pd/COF-LZU1, was accordingly synthesized, which showed excellent catalytic activity in catalyzing the Suzuki-Miyaura coupling reaction. The superior utility of Pd/COF-LZU1 in catalysis was elucidated by the broad scope of the reactants and the excellent yields (96-98%) of the reaction products, together with the high stability and easy recyclability of the catalyst. We expect that our approach will further boost research on designing and employing functional COF materials for catalysis.
Department
[Ding, San-Yuan;
Gao, Jia;
Wang, Qiong;
Zhang, Yuan;
Wang, Wei] Lanzhou Univ, State Key Lab Appl Organ Chem, Coll Chem & Chem Engn, Lanzhou 730000, Gansu, Peoples R China;
[Wang, Qiong;
Song, Wei-Guo] Chinese Acad Sci, Inst Chem, Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China;
[Wang, Qiong;
Song, Wei-Guo] Chinese Acad Sci, Beijing Natl Lab Mol Sci BNLMS, Beijing 100190, Peoples R China;
[Su, Cheng-Yong] Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Guangdong, Peoples R China...更多
Subject AreaChemistry
Project NumberNational Natural Science Foundation of China [20933009, 20972064] ; Chinese Ministry of Education [309028] ; 111 Project
Funding Project国家自然科学基金项目 ; 教育部科学技术研究重大项目 ; 高等学校学科创新引智计划(111计划)
Funding OrganizationNational Natural Science Foundation of China [20933009, 20972064]; Chinese Ministry of Education [309028]; 111 Project ; NSFC ; SAFEA ; MOE
DOI10.1021/ja206846p
ISSN0002-7863
SubtypeArticle
Language英语
WOS IDWOS:000298719800048
EI ID20115014597783
PMID 22026454
First Inst
Citation statistics
Cited Times:696[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.lzu.edu.cn/handle/262010/76261
Collection化学化工学院
Corresponding AuthorWang, W (reprint author), Lanzhou Univ, State Key Lab Appl Organ Chem, Coll Chem & Chem Engn, Lanzhou 730000, Gansu, Peoples R China.
Recommended Citation
GB/T 7714
Ding, SY,Gao, J,Wang, Q,et al. Construction of Covalent Organic Framework for Catalysis: Pd/COF-LZU1 in Suzuki-Miyaura Coupling Reaction[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2011,133(49).
APA Ding, SY.,Gao, J.,Wang, Q.,Zhang, Y.,Song, WG.,...&Wang, W .(2011).Construction of Covalent Organic Framework for Catalysis: Pd/COF-LZU1 in Suzuki-Miyaura Coupling Reaction.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,133(49).
MLA Ding, SY,et al."Construction of Covalent Organic Framework for Catalysis: Pd/COF-LZU1 in Suzuki-Miyaura Coupling Reaction".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 133.49(2011).
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