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Development and Application of a New General Method for the Asymmetric Synthesis of (E)-(2-En-3-ynyl)-amines
Yin, C; Hui, XP(惠新平); Xu, PF(许鹏飞); Niu, LF; Chen, YF; Wang, BH; Hui, XP (reprint author), Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China.
2009-02
发表期刊ADVANCED SYNTHESIS & CATALYSIS
ISSN1615-4150
卷号351期号:3
出版者WILEY
摘要The first direct approach for the asymmetric synthesis of (E)-2-arylidene-1,4-diphenylbut-3-yn-1-amines by addition of alkynylzinc to chiral N-tert-butylsulfinylimines is reported with excellent diastereoselectivity and good yield. This asymmetric addition reaction provides a practical, economical and concise synthesis of multifunctional molecules with the 1,3-enyne side chain and an amino group. In addition, this methodology can be applied to the synthesis of substituted vinyl iodide compounds, and substituted chiral dihydropyrroles.
出版地WEINHEIM
关键词Alkynes Asymmetric Synthesis Cyclization Diethylzinc N-tert-butanesulfinylimines
学科领域Chemistry
作者部门[Yin, Chao;
Hui, Xin-Ping;
Xu, Peng-Fei;
Niu, Liang-Feng;
Chen, Yong-Fei] Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China;
[Wang, Binghe] Georgia State Univ, Dept Chem, Atlanta, GA 30302 USA
DOI10.1002/adsc.200800642
文章类型Article
收录类别SCIE
所属项目编号National Natural Science Foundation of China (NSFC) [20772051, 20702022] ; Ministry of Education of P. R. China [NCET-05-0880]
语种英语
资助项目国家自然科学基金项目 ; 新世纪优秀人才支持计划
项目资助者National Natural Science Foundation of China (NSFC) [20772051, 20702022]; Ministry of Education of P. R. China [NCET-05-0880] ; NSFC ; MOE
WOS记录号WOS:000264058900012
第一机构
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文献类型期刊论文
条目标识符http://ir.lzu.edu.cn/handle/262010/77209
Collection化学化工学院
通讯作者Hui, XP (reprint author), Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China.
Recommended Citation:
GB/T 7714
Yin, C,Hui, XP,Xu, PF,et al. Development and Application of a New General Method for the Asymmetric Synthesis of (E)-(2-En-3-ynyl)-amines[J]. ADVANCED SYNTHESIS & CATALYSIS,2009,351(3).
APA Yin, C.,Hui, XP.,Xu, PF.,Niu, LF.,Chen, YF.,...&Hui, XP .(2009).Development and Application of a New General Method for the Asymmetric Synthesis of (E)-(2-En-3-ynyl)-amines.ADVANCED SYNTHESIS & CATALYSIS,351(3).
MLA Yin, C,et al."Development and Application of a New General Method for the Asymmetric Synthesis of (E)-(2-En-3-ynyl)-amines".ADVANCED SYNTHESIS & CATALYSIS 351.3(2009).
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