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题名: Development and Application of a New General Method for the Asymmetric Synthesis of (E)-(2-En-3-ynyl)-amines
作者: Yin, C ; Hui, XP(惠新平) ; Xu, PF(许鹏飞) ; Niu, LF ; Chen, YF ; Wang, BH
收录类别: SCIE
出版日期: 2009-02
刊名: ADVANCED SYNTHESIS & CATALYSIS
卷号: 351, 期号:3
英文摘要: The first direct approach for the asymmetric synthesis of (E)-2-arylidene-1,4-diphenylbut-3-yn-1-amines by addition of alkynylzinc to chiral N-tert-butylsulfinylimines is reported with excellent diastereoselectivity and good yield. This asymmetric addition reaction provides a practical, economical and concise synthesis of multifunctional molecules with the 1,3-enyne side chain and an amino group. In addition, this methodology can be applied to the synthesis of substituted vinyl iodide compounds, and substituted chiral dihydropyrroles.
关键词: alkynes ; asymmetric synthesis ; cyclization ; diethylzinc ; N-tert-butanesulfinylimines
作者部门: [Yin, Chao ; Hui, Xin-Ping ; Xu, Peng-Fei ; Niu, Liang-Feng ; Chen, Yong-Fei] Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China ; [Wang, Binghe] Georgia State Univ, Dept Chem, Atlanta, GA 30302 USA
通讯作者: Hui, XP (reprint author), Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China.
学科分类: Chemistry
语种: 英语
DOI: 10.1002/adsc.200800642
ISSN号: 1615-4150
WOS记录号: WOS:000264058900012
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.lzu.edu.cn/handle/262010/77209
Appears in Collections:化学化工学院_期刊论文

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Yin, C; Hui, XP; Xu, PF; Niu, LF; Chen, YF; Wang, BH.Development and Application of a New General Method for the Asymmetric Synthesis of (E)-(2-En-3-ynyl)-amines,ADVANCED SYNTHESIS & CATALYSIS,2009,351(3):
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