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Synthesis and crystal structure of a new mixed-valence complex of copper (I, II) alpha-methacrylate with triphenylphosphine and methanol
Wang, YY; Shi, Q; Shi, QZ(史启祯); Gao, YC(高忆慈); Zhou, ZY
1998-11
发表期刊CHINESE CHEMICAL LETTERS
ISSN1001-8417
卷号9期号:11
期刊主办单位中国化学会
出版者CHINESE CHEMICAL SOCIETY
摘要Copper (II) alpha-methacryrate reacts with triphenylphosphine to form mixed-valence copper (I,II) complex Cu-4(CH2=C(CH3)COO)(6)(PPh3)(4)(CH3OH)(2) in methanol solution. The crystal and molecular structure of the complex has been determined by single crystal X-ray structural analysis. This material forms pale green crystals with triclinic symmetry, space group Pi, a=1.3567 (2) nm, b=1.3946 (3) nm, c=1.4569 (3) nm, alpha=66.069 (14)degrees, beta=84.234 (14)degrees, gamma=69.975 (13)degrees, R=0.0536.
出版地BEIJING
关键词mixed-valence complex synthesis crystal structure
学科领域Chemistry
作者部门NW Univ Xian, Dept Chem, Xian 710069, Peoples R China;
Lanzhou Univ, Dept Chem, Lanzhou 730000, Peoples R China;
Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China
文章类型Article
收录类别SCIE
语种英语
WOS记录号WOS:000083722900028
第一机构
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文献类型期刊论文
条目标识符http://ir.lzu.edu.cn/handle/262010/79720
Collection化学化工学院
Recommended Citation:
GB/T 7714
Wang, YY,Shi, Q,Shi, QZ,et al. Synthesis and crystal structure of a new mixed-valence complex of copper (I, II) alpha-methacrylate with triphenylphosphine and methanol[J]. CHINESE CHEMICAL LETTERS,1998,9(11).
APA Wang, YY,Shi, Q,Shi, QZ,Gao, YC,&Zhou, ZY.(1998).Synthesis and crystal structure of a new mixed-valence complex of copper (I, II) alpha-methacrylate with triphenylphosphine and methanol.CHINESE CHEMICAL LETTERS,9(11).
MLA Wang, YY,et al."Synthesis and crystal structure of a new mixed-valence complex of copper (I, II) alpha-methacrylate with triphenylphosphine and methanol".CHINESE CHEMICAL LETTERS 9.11(1998).
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