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题名: Synthesis and crystal structure of a new mixed-valence complex of copper (I, II) alpha-methacrylate with triphenylphosphine and methanol
作者: Wang, YY; Shi, Q; Shi, QZ(史启祯); Gao, YC(高忆慈); Zhou, ZY
收录类别: SCIE
出版日期: 1998-11
刊名: CHINESE CHEMICAL LETTERS
卷号: 9, 期号:11
期刊主办单位: 中国化学会
出版者: CHINESE CHEMICAL SOCIETY
出版地: BEIJING
英文摘要: Copper (II) alpha-methacryrate reacts with triphenylphosphine to form mixed-valence copper (I,II) complex Cu-4(CH2=C(CH3)COO)(6)(PPh3)(4)(CH3OH)(2) in methanol solution. The crystal and molecular structure of the complex has been determined by single crystal X-ray structural analysis. This material forms pale green crystals with triclinic symmetry, space group Pi, a=1.3567 (2) nm, b=1.3946 (3) nm, c=1.4569 (3) nm, alpha=66.069 (14)degrees, beta=84.234 (14)degrees, gamma=69.975 (13)degrees, R=0.0536.
关键词: mixed-valence complex ; synthesis ; crystal structure
作者部门: NW Univ Xian, Dept Chem, Xian 710069, Peoples R China ; Lanzhou Univ, Dept Chem, Lanzhou 730000, Peoples R China ; Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China
学科分类: Chemistry
文章类型: Article
语种: 英语
ISSN号: 1001-8417
WOS记录号: WOS:000083722900028
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内容类型: 期刊论文
URI标识: http://ir.lzu.edu.cn/handle/262010/79720
Appears in Collections:化学化工学院_期刊论文

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Wang, YY; Shi, Q; Shi, QZ; Gao, YC; Zhou, ZY.Synthesis and crystal structure of a new mixed-valence complex of copper (I, II) alpha-methacrylate with triphenylphosphine and methanol,CHINESE CHEMICAL LETTERS,1998,9(11):
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