| Tuning Hierarchical ZSM-5 Zeolite for Both Gas- And Liquid-Phase Biorefining | |
| Zhao, Shufang1; Wang, Wei David2; Wang, Lizhuo1; Schwieger, Wilhelm3; Wang, Wei2; Huang, Jun1 | |
| 2020 | |
| Source Publication | ACS Catalysis Impact Factor & Quartile |
| ISSN | 21555435 |
| Volume | 10Issue:2Pages:1185-1194 |
| Abstract | A hierarchical ZSM-5 zeolite with an adjustable mesoporous size is required for many chemical processes including the biorefining of big biomass compounds. In this research, a simple and high-efficiency hard template method has been successfully developed by adopting carbon nanoparticles obtained from carbonation of polyethylene oxide and urea. The abundant -C-O-C- groups on the surface of carbon nanoparticles provide the high hydrophilicity (from -C-O-C- to -C-O-H) in the alkaline synthetic gel solution, which promotes the synthesis of hierarchical ZSM-5 zeolite and the aluminum condensation in the silica framework to improve the Brønsted acidity. The as-synthesized hierarchical zeolites exhibited two sets of channel systems: micropores (∼0.55 nm) are from the MFI framework network, and mesopores (∼12.5 and ∼34.5 nm) result from carbon nanoparticles of 10-40 nm in size, respectively. The hierarchical ZSM-5 with minimized extraframework aluminum species showed catalytic performance with high ethanol conversion (100%) and high stability (lifetime above 30 h) in the ethanol to olefins conversion. Importantly, the diffusion efficiency in ZSM-5 with mesoporous size was remarkably improved, compared to the catalyst with mesoporous size ∼12.5 nm. As the benzylation of mesitylene with benzyl alcohol, the ZSM-5 (∼34.5 nm) sample showed the highest conversion in benzyl alcohol (82.0%) and selectivity in 2-benzyl-1,3,5-trimethylbenzene (74.3%). © 2019 American Chemical Society. |
| Keyword | hierarchical ZSM-5 zeolites carbon particles Bronsted acidity ethanol dehydration benzylation |
| DOI | 10.1021/acscatal.9b04104 |
| Indexed By | SCIE ; EI |
| Language | 英语 |
| Funding Project | Australian Research Council[DP180104010] ; University of Sydney[] ; [] |
| WOS Research Area | Chemistry |
| WOS Subject | Chemistry, Physical |
| WOS ID | WOS:000508466700023 |
| Publisher | American Chemical Society |
| EI Accession Number | 20200508110098 |
| EI Keywords | Alkalinity ; Aluminum ; Carbon ; Efficiency ; Ethanol ; Mesoporous materials ; Nanoparticles ; Polyethylene oxides ; Refining ; Silica ; Synthesis (chemical) ; Urea ; Zeolites |
| EI Classification Number | Aluminum:541.1 ; Nanotechnology:761 ; Chemistry, General:801.1 ; Chemical Reactions:802.2 ; Chemical Products Generally:804 ; Organic Polymers:815.1.1 ; Production Engineering:913.1 ; Solid State Physics:933 ; Systems Science:961 |
| Original Document Type | Journal article (JA) |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | https://ir.lzu.edu.cn/handle/262010/417125 |
| Collection | 兰州大学 |
| Corresponding Author | Huang, Jun |
| Affiliation | 1.Laboratory for Catalysis Engineering, School of Chemical and Biomolecular Engineering, Sydney Nano Institute, University of Sydney, Sydney; NSW; 2006, Australia 2.State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, Gansu; 730000, China 3.Institute of Chemical Reaction Engineering, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstr. 3, Erlangen; 91058, Germany |
| Recommended Citation GB/T 7714 | Zhao, Shufang,Wang, Wei David,Wang, Lizhuo,et al. Tuning Hierarchical ZSM-5 Zeolite for Both Gas- And Liquid-Phase Biorefining[J]. ACS Catalysis,2020,10(2):1185-1194. |
| APA | Zhao, Shufang,Wang, Wei David,Wang, Lizhuo,Schwieger, Wilhelm,Wang, Wei,&Huang, Jun.(2020).Tuning Hierarchical ZSM-5 Zeolite for Both Gas- And Liquid-Phase Biorefining.ACS Catalysis,10(2),1185-1194. |
| MLA | Zhao, Shufang,et al."Tuning Hierarchical ZSM-5 Zeolite for Both Gas- And Liquid-Phase Biorefining".ACS Catalysis 10.2(2020):1185-1194. |
| Files in This Item: | |||||
| File Name/Size | DocType | Version | Access | License | |
| 10.1021@acscatal.9b0（2074KB） | 期刊论文 | 出版稿 | 限制开放 | CC BY-NC-SA | View Application Full Text |
