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A Flexible Aromatic Tetracarboxylate as a New Linker for Coordination Polymers
Gu, Wenjun1; Gu, Jinzhong2; Kirillov, Alexander M.3,4
2020-02
Source PublicationCrystals   Impact Factor & Quartile Of Published Year  The Latest Impact Factor & Quartile
ISSN2073-4352
Volume10Issue:2
page numbers10
AbstractTwo new cadmium(II)-based materials, featuring two-dimensional (2D) [Cd-2(mu(6)-deta)(bpy)(H2O)](n) (1) and three-dimensional (3D) [Cd-2(mu(5)-deta)(bpy)(2)(H2O)](n) (2) structures, were constructed by the hydrothermal method from 2,3 ',4 ',5-diphenyl ether tetracarboxylic acid (H(4)deta) as an unexplored linker in research on coordination polymers (CPs) and 2,2 '-bipyridine (bpy) as a mediator of crystallization. Microcrystalline samples of 1 and 2 were analyzed by IR/PXRD/EA/TGA and X-ray diffraction using single crystals. Structures and topologies of CPs 1 and 2 were established, revealing a 4,6L45 topological layer in 1 and a 3,5T1 topological framework in 2. Structural differences for 1 and 2 are attributed to distinct molar ratios between Cd2+ and bpy during the hydrothermal synthesis. Luminescence and thermal behavior of the obtained materials were also investigated. The present work opens up the use of an unexplored 2,3 ',4 ',5-diphenyl ether tetracarboxylic acid as a versatile and flexible linker toward the generation of functional coordination polymer materials.
Keywordcoordination polymers (CPs) metal-organic frameworks (MOFs) carboxylic acids hydrothermal generation topological analysis luminescent materials
PublisherMDPI
DOI10.3390/cryst10020084
Indexed BySCIE
Language英语
Funding ProjectPortugal 2020[LISBOA-01-0145-FEDER-029697][UIDB/00100/2020]
WOS Research AreaCrystallography ; Materials Science
WOS SubjectCrystallography ; Materials Science, Multidisciplinary
WOS IDWOS:000519704700087
PublisherMDPI
Original Document TypeArticle
Citation statistics
Document Type期刊论文
Identifierhttps://ir.lzu.edu.cn/handle/262010/417639
Collection兰州大学
Corresponding AuthorGu, Jinzhong; Kirillov, Alexander M.
Affiliation
1.Fudan Univ, Sch Life Sci, Shanghai 200438, Peoples R China
2.Lanzhou Univ, Colleague Chem & Chem Engn, Lanzhou 730000, Peoples R China
3.Univ Lisbon, Inst Super Tecn, Ctr Quim Enstrutural, Ave Rovisco Pais, P-1049001 Lisbon, Portugal
4.Peopless Friendship Univ Russia RUDN Univ, Res Inst Chem, 6Miklukho Maklaya St, Moscow 117198, Russia
Recommended Citation
GB/T 7714
Gu, Wenjun,Gu, Jinzhong,Kirillov, Alexander M.. A Flexible Aromatic Tetracarboxylate as a New Linker for Coordination Polymers[J]. Crystals,2020,10(2).
APA Gu, Wenjun,Gu, Jinzhong,&Kirillov, Alexander M..(2020).A Flexible Aromatic Tetracarboxylate as a New Linker for Coordination Polymers.Crystals,10(2).
MLA Gu, Wenjun,et al."A Flexible Aromatic Tetracarboxylate as a New Linker for Coordination Polymers".Crystals 10.2(2020).
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