| Rhodium-Catalyzed Reductive trans-Alkylacylation of Internal Alkynes via a Formal Carborhodation/C-H Carbonylation Cascade | |
| Yang, Yu-Zhong1; He, De-Liang1; Li, Jin-Heng1,2,3,4 | |
| 2021-07-02 | |
| Online publication date | 2021-06 |
| Source Publication | ORGANIC LETTERS Impact Factor & Quartile |
| ISSN | 1523-7060 |
| EISSN | 1523-7052 |
| Volume | 23Issue:13Pages:5039-5043 |
| page numbers | 5 |
| Abstract | A rhodium-catalyzed reductive annulation cascade reaction that consists of a formal anti-carborhodation of a C C bond and an aromatic C-H carbonylation cascade for producing cyclopenta[de]quinoline-2,5(1H,3H)-diones is described. This method uses the Mn reductant to reductively regenerate the active rhodium species, hence obviating the need for prefunctionalization, and represents a new route to the carbonylation of aromatic C-H bonds with alkynes leading to aryl vinyl ketone frameworks. |
| Publisher | AMER CHEMICAL SOC |
| DOI | 10.1021/acs.orglett.1c01568 |
| Indexed By | SCOPUS ; SCIE ; IC |
| Language | 英语 |
| WOS Research Area | Chemistry |
| WOS Subject | Chemistry, Organic |
| WOS ID | WOS:000670661700021 |
| Original Document Type | Article |
| PMID | 34114822 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | https://ir.lzu.edu.cn/handle/262010/470572 |
| Collection | 兰州大学 |
| Corresponding Author | He, De-Liang; Li, Jin-Heng |
| Affiliation | 1.Hunan Univ, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Peoples R China; 2.Nanchang Hangkong Univ, Key Lab Jiangxi Prov Persistent Pollutants Contro, Nanchang 330063, Jiangxi, Peoples R China; 3.Hunan Normal Univ, Key Lab Chem Biol & Tradit Chinese Med Res, Minist Educ, Changsha 410081, Peoples R China; 4.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Yang, Yu-Zhong,He, De-Liang,Li, Jin-Heng. Rhodium-Catalyzed Reductive trans-Alkylacylation of Internal Alkynes via a Formal Carborhodation/C-H Carbonylation Cascade[J]. ORGANIC LETTERS,2021,23(13):5039-5043. |
| APA | Yang, Yu-Zhong,He, De-Liang,&Li, Jin-Heng.(2021).Rhodium-Catalyzed Reductive trans-Alkylacylation of Internal Alkynes via a Formal Carborhodation/C-H Carbonylation Cascade.ORGANIC LETTERS,23(13),5039-5043. |
| MLA | Yang, Yu-Zhong,et al."Rhodium-Catalyzed Reductive trans-Alkylacylation of Internal Alkynes via a Formal Carborhodation/C-H Carbonylation Cascade".ORGANIC LETTERS 23.13(2021):5039-5043. |
| Files in This Item: | There are no files associated with this item. | ||||
