| Redox Neutral Radical-Relay Nickel-Catalyzed Remote Carbonylation | |
| Li, Ming1; Gao, Fan1; Miao, Dong-Yu1; Chen, Dong-ping1; Li, Shun-Xi1; Qiu, Yi-Feng1; Quan, Zheng-Jun1; Wang, Xi-Cun1; Liang, Yong-Min2 | |
| 2023-04-07 | |
| Online publication date | 2023-03 |
| Source Publication | ORGANIC LETTERS Impact Factor & Quartile |
| ISSN | 1523-7060 |
| Volume | 25Issue:13Pages:2306-2311 |
| page numbers | 6 |
| Abstract | A novel and efficient method for the catalytic installation of a carbonyl group via remote radical coupling is disclosed. The nickel-catalyzed reaction proceeds to undergo a sequential single-electron transfer, 1,5-hydrogen atom transfer, and carbonyl insertion, thus providing the alpha-substituted ketone. Further, this reaction could be carried out smoothly under normal pressure and redox-neutral conditions, and demonstrated functional-group compatibility and excellent site-selectivity. |
| Publisher | AMER CHEMICAL SOC |
| DOI | 10.1021/acs.orglett.3c00654 |
| Indexed By | SCIE ; IC |
| Language | 英语 |
| WOS Research Area | Chemistry |
| WOS Subject | Chemistry, Organic |
| WOS ID | WOS:000962875700001 |
| Original Document Type | Article |
| PMID | 36988237 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | https://ir.lzu.edu.cn/handle/262010/501578 |
| Collection | 兰州大学 |
| Corresponding Author | Li, Ming; Quan, Zheng-Jun; Wang, Xi-Cun; Liang, Yong-Min |
| Affiliation | 1.Northwest Normal Univ, Coll Chem & Chem Engn, Lanzhou 730070, Gansu, Peoples R China; 2.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Li, Ming,Gao, Fan,Miao, Dong-Yu,et al. Redox Neutral Radical-Relay Nickel-Catalyzed Remote Carbonylation[J]. ORGANIC LETTERS,2023,25(13):2306-2311. |
| APA | Li, Ming.,Gao, Fan.,Miao, Dong-Yu.,Chen, Dong-ping.,Li, Shun-Xi.,...&Liang, Yong-Min.(2023).Redox Neutral Radical-Relay Nickel-Catalyzed Remote Carbonylation.ORGANIC LETTERS,25(13),2306-2311. |
| MLA | Li, Ming,et al."Redox Neutral Radical-Relay Nickel-Catalyzed Remote Carbonylation".ORGANIC LETTERS 25.13(2023):2306-2311. |
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