|Doping and pretreatment optimized the adsorption of *OCHO on bismuth for the electrocatalytic reduction of CO2 to formate|
|Tian, Meng1; Wu, Shanshan1; Hu, Yang1; Mu, Zhaori1; Li, Zhi1; Hou, Yichao1; Xi, PX(席聘贤)1; Yan, Chun-Hua1,2|
|Online publication date||2023-02
Impact Factor & Quartile|
|Abstract||Electrocatalytic reduction of CO2 to formate is considered as a promising method to achieve carbon neutrality, and the introduction of heteroatoms is an effective strategy to improve the catalytic activity and selectivity of catalysts. However, the structural reconstruction behavior of catalysts driven by voltage is usually ignored. Therefore, we used Cu/Bi2S3 as a model to reveal the dynamic reduction process in different atmospheric environments. The catalyst showed an outstanding faradaic efficiency of 94% for formate and a long-term stability of 100 h, and exhibited a high current density of 280 mA cm−2 in a flow cell. The experimental results and theoretical calculations show that the introduction of copper enhances the adsorption of CO2, accelerates the charge transfer and reduces the formation barrier of *OCHO, thus promoting the formation of formate. This work draws attention to the effects of saturated gases in the electrolyte during structural evolution and provides a possibility for designing catalysts with high catalytic activity. © 2023 The Royal Society of Chemistry.|
|Publisher||Royal Society of Chemistry
|WOS Research Area||Chemistry
; Science & Technology - Other Topics
; Materials Science
|WOS Subject||Chemistry, Multidisciplinary
; Nanoscience & Nanotechnology
; Materials Science, Multidisciplinary
; Physics, Applied
|EI Accession Number||20230813626269
|EI Keywords||Carbon dioxide
|EI Classification Number||549.3 Nonferrous Metals and Alloys excluding Alkali and Alkaline Earth Metals
; 702 Electric Batteries and Fuel Cells
; 802.2 Chemical Reactions
; 803 Chemical Agents and Basic Industrial Chemicals
; 804 Chemical Products Generally
; 804.2 Inorganic Compounds
|Original Document Type||Journal article (JA)
|Corresponding Author||Xi, Pinxian|
|Affiliation||1.State Key Laboratory of Applied Organic Chemistry, Frontiers Science Center for Rare Isotopes, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou; 730000, China;|
2.Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, PKU-HKU Joint Laboratory in Rare Earth Materials and Bioinorganic Chemistry, College of Chemistry and Molecular Engineering Peking University, Beijing; 100871, China
|First Author Affilication||College of Chemistry and Chemical Engineering
|Corresponding Author Affilication||College of Chemistry and Chemical Engineering
Tian, Meng,Wu, Shanshan,Hu, Yang,et al. Doping and pretreatment optimized the adsorption of *OCHO on bismuth for the electrocatalytic reduction of CO2 to formate[J].
Tian, Meng.,Wu, Shanshan.,Hu, Yang.,Mu, Zhaori.,Li, Zhi.,...&Yan, Chun-Hua.(2023).Doping and pretreatment optimized the adsorption of *OCHO on bismuth for the electrocatalytic reduction of CO2 to formate.Nanoscale,15(9),4477-4487.
Tian, Meng,et al."Doping and pretreatment optimized the adsorption of *OCHO on bismuth for the electrocatalytic reduction of CO2 to formate".Nanoscale 15.9(2023):4477-4487.
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