兰州大学机构库
Nitrogen-doped porous carbon encapsulates multivalent cobalt-nickel as oxygen reduction reaction catalyst for zinc-air battery
Zhou, Quan1; Miao, Song1; Xue, Tong1; Liu, Yipu2; Li, Hua3; Yan, Xiang-Hui1; Zou, Zhong-Li1; Wang, Bei-Ping1; Lu, You-Jun1; Han, Feng-Lan1
2023-10-15
Online publication date2023-06
Source PublicationJOURNAL OF COLLOID AND INTERFACE SCIENCE   Impact Factor & Quartile
ISSN0021-9797
Volume648Pages:511-519
page numbers9
AbstractIn this study, we present a bimetallic ion coexistence encapsulation strategy employing hexadecyl trimethyl ammonium bromide (CTAB) as a mediator to anchor cobalt–nickel (CoNi) bimetals in nitrogen-doped porous carbon cubic nanoboxes (CoNi@NC). The fully encapsulated and uniformly dispersed CoNi nanoparticles with the improved density of active sites help to accelerate the oxygen reduction reaction (ORR) kinetics and provide an efficient charge/mass transport environment. Zinc-air battery (ZAB) equipped CoNi@NC as cathode exhibits an open-circuit voltage of 1.45 V, a specific capacity of 870.0 mAh g−1, and a power density of 168.8 mW cm−2. Moreover, the two CoNi@NC-based ZABs in series display a stable discharge specific capacity of 783.0 mAh g−1, as well as a large peak power density of 387.9 mW cm−2. This work provides an effective way to tune the dispersion of nanoparticles to boost active sites in nitrogen-doped carbon structure, and enhance the ORR activity of bimetallic catalysts. © 2023 Elsevier Inc.
KeywordBimetals Binary alloys Carbon Catalyst activity Cobalt Cobalt alloys Doping (additives) Nanoparticles Nickel Nitrogen Open circuit voltage Oxygen Porous materials Reaction kinetics Zinc Zinc air batteries Cobalt-nickel Cobalt–nickel bimetal Doped carbons Metalorganic frameworks (MOFs) N-doped N-doped carbon Nitrogen-doped Oxygen reduction reaction Porous carbons Zinc-air battery
PublisherAcademic Press Inc.
DOI10.1016/j.jcis.2023.05.164
Indexed ByEI ; SCIE
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Physical
WOS IDWOS:001020596900001
EI Accession Number20232414232963
EI KeywordsElectrolytic reduction
EI Classification Number531 Metallurgy and Metallography ; 533.1 Ore Treatment ; 546.3 Zinc and Alloys ; 548.1 Nickel ; 549.3 Nonferrous Metals and Alloys excluding Alkali and Alkaline Earth Metals ; 702.1.2 Secondary Batteries ; 761 Nanotechnology ; 802.2 Chemical Reactions ; 803 Chemical Agents and Basic Industrial Chemicals ; 804 Chemical Products Generally ; 933 Solid State Physics ; 951 Materials Science
Original Document TypeJournal article (JA)
PMID 37307607
Citation statistics
Document Type期刊论文
Identifierhttps://ir.lzu.edu.cn/handle/262010/529642
Collection兰州大学
Corresponding AuthorXue, Tong; Liu, Yipu; Li, Hua
Affiliation
1.National and Local Joint Engineering Research Center of Advanced Carbon Based Ceramics Preparation Technology, Collaborative Innovation Center for High Value Utilization of Industrial By-products, School of Materials Science and Engineering, North Minzu University, Yinchuan; 750021, China;
2.State Key Laboratory of Marine Resource Utilization in South China Sea, Hainan University, Haikou; 570228, China;
3.School of Materials and Energy, Electron Microscopy Centre, Lanzhou University, Lanzhou; 730000, China
Corresponding Author AffilicationLanzhou University
Recommended Citation
GB/T 7714
Zhou, Quan,Miao, Song,Xue, Tong,et al. Nitrogen-doped porous carbon encapsulates multivalent cobalt-nickel as oxygen reduction reaction catalyst for zinc-air battery[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE,2023,648:511-519.
APA Zhou, Quan.,Miao, Song.,Xue, Tong.,Liu, Yipu.,Li, Hua.,...&Han, Feng-Lan.(2023).Nitrogen-doped porous carbon encapsulates multivalent cobalt-nickel as oxygen reduction reaction catalyst for zinc-air battery.JOURNAL OF COLLOID AND INTERFACE SCIENCE,648,511-519.
MLA Zhou, Quan,et al."Nitrogen-doped porous carbon encapsulates multivalent cobalt-nickel as oxygen reduction reaction catalyst for zinc-air battery".JOURNAL OF COLLOID AND INTERFACE SCIENCE 648(2023):511-519.
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