| Mesoporous Mixed-Metal-Organic Framework Incorporating a [Ru(Phen)(3)](2+) Photosensitizer for Highly Efficient Aerobic Photocatalytic Oxidative Coupling of Amines | |
| Bai, Dongjie1; Qiu, Jinlin1; Li, Jingzhe1; Zhou, Shengbin1; Cui, Xiang2,3; Tang, Xiaoliang1,2,3; Tang, Yu1; Liu, Weisheng1,2,3; Chen, Banglin4 | |
| 2023-06-13 | |
| Source Publication | ACS Applied Materials & Interfaces Impact Factor & Quartile |
| ISSN | 1944-8244 |
| Abstract | [Ru(Phen)(3)](2+) (phen = phenanthroline)asa very classical photosensitizer possesses strong absorption in thevisible range and facilitates photoinduced electron transfer, whichplays a vital role in regulating photochemical reactions. However,it remains a significant challenge to utilize more adequately andexploit more efficiently the ruthenium-based materials due to theuniqueness, scarcity, and nonrenewal of the noble metal. Here, weintegrate the intrinsic advantages of the ruthenium-based photosensitizerand mesoporous metal-organic frameworks (meso-MOFs) into a[Ru(Phen)(3)](2+) photosensitizer-embedded heterometallicNi(II)/Ru(II) meso-MOF (LTG-NiRu) via the metalloligandapproach. LTG-NiRu, with an extremely robust frameworkand a large one-dimensional (1D) channel, not only makes rutheniumphotosensitizer units anchored in the inner wall of meso-MOF tubesto circumvent the problem of product/catalyst separation and recyclingof catalysts in heterogeneous systems but also exhibits exceptionalactivities for the aerobic photocatalytic oxidative coupling of aminederivatives as a general photocatalyst. The conversion of the light-inducedoxidative coupling reaction for various benzylamines is similar to 100%in 1 h, and more than 20 chemical products generated by photocatalyticoxidative cycloaddition of N-substituted maleimides and N,N-dimethylaniline can be synthesized easily inthe presence of LTG-NiRu upon visible light irradiation.Moreover, recycling experiments demonstrate that LTG-NiRu is an excellent heterogeneous photocatalyst with high stabilityand excellent reusability. LTG-NiRu represents a greatpotential photosensitizer-based meso-MOF platform with an efficientaerobic photocatalytic oxidation function that is convenient for gram-scalesynthesis. |
| Keyword | photosensitizing MOFs photocatalysis oxidativecoupling mesoporous materials gram-scale synthesis |
| Publisher | AMER CHEMICAL SOC |
| DOI | 10.1021/acsami.3c05397 |
| Indexed By | SCIE |
| Language | 英语 |
| WOS Research Area | Science & Technology - Other Topics ; Materials Science |
| WOS Subject | Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
| WOS ID | WOS:001006551000001 |
| Original Document Type | Article ; Early Access |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | https://ir.lzu.edu.cn/handle/262010/530055 |
| Collection | 兰州大学 |
| Corresponding Author | Tang, Xiaoliang; Chen, Banglin |
| Affiliation | 1.Lanzhou Univ, Coll Chem & Chem Engn, Frontiers Sci Ctr Rare Isotopes, State Key Lab Appl Organ Chem,Key Lab Nonferrous M, Lanzhou 730000, Peoples R China; 2.Qinghai Normal Univ, Acad Plateau Sci & Sustainabil, Peoples Govt Qinghai Prov, Xining 810016, Peoples R China; 3.Qinghai Normal Univ, Beijing Normal Univ, Coll Chem & Chem Engn, Xining 810016, Peoples R China; 4.Fujian Normal Univ, Coll Chem & Mat Sci, Fujian Prov Key Lab Polymer Mat, Fuzhou 350007, Peoples R China |
| Recommended Citation GB/T 7714 | Bai, Dongjie,Qiu, Jinlin,Li, Jingzhe,et al. Mesoporous Mixed-Metal-Organic Framework Incorporating a [Ru(Phen)(3)](2+) Photosensitizer for Highly Efficient Aerobic Photocatalytic Oxidative Coupling of Amines[J]. ACS Applied Materials & Interfaces,2023. |
| APA | Bai, Dongjie.,Qiu, Jinlin.,Li, Jingzhe.,Zhou, Shengbin.,Cui, Xiang.,...&Chen, Banglin.(2023).Mesoporous Mixed-Metal-Organic Framework Incorporating a [Ru(Phen)(3)](2+) Photosensitizer for Highly Efficient Aerobic Photocatalytic Oxidative Coupling of Amines.ACS Applied Materials & Interfaces. |
| MLA | Bai, Dongjie,et al."Mesoporous Mixed-Metal-Organic Framework Incorporating a [Ru(Phen)(3)](2+) Photosensitizer for Highly Efficient Aerobic Photocatalytic Oxidative Coupling of Amines".ACS Applied Materials & Interfaces (2023). |
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