| In-situ growth of Mn2O3/MnCo2O4 on 3D nickel foam as a novel heterogeneous composites peroxymonosulfate activator for the degradation of levofloxacin: Performance, stability and mechanism | |
| Song, Lixian2; Cheng, Xiuwen1,2; Yang, Ying2; Hou, Yilong2; Gan, Xinrui1; Wang, Ce2; Shang, Jiangwei1,2 | |
| 2023-09-01 | |
| Source Publication | CHEMICAL ENGINEERING JOURNAL Impact Factor & Quartile |
| ISSN | 1385-8947 |
| Volume | 471 |
| Abstract | The in-situ generation of nanostructured materials on the metal-based carriers nickel foam (NF) is a novel technique for water remediation materials. In this study, Mn2O3/MnCo2O4 materials were successfully produced in situ on three-dimensional (3D) NF substrates using hydrothermal followed by calcination. Mn2O3/MnCo2O4@NF can synergistically activate peroxymonosulfate (PMS), leading to efficient levofloxacin degradation (LEVO). At optimal conditions (catalyst dosage of 0.50 × 0.50 cm2, PMS dosage of 0.30 g/L, PH = 6.75), the removal rate of LEVO (10 mg/L) by Mn2O3/MnCo2O4@NF could obtain 91.8 % within 30 min (reaction kinetic rate constant (Kobs) = 0.2063 min−1). In addition to acting as a support carrier and exposing an abundance of active sites, NF also mediates and facilitates electron transport, inhibits metal ions' leaching, and improves recycling's effectiveness. The system can remove contaminants through a combination of radical (SO4·–, ·OH) and non-free radical (1O2, surface electron transfer) pathways. Eleven intermediates in the degradation of LEVO were identified via the HPLC-MS. The biotoxicity of the intermediates was measured using the Ecological Structure-Activity Relationship (ECOSAR) technique, demonstrating that the catalyst is environmentally friendly and safe. The study has broad applicability and prospect, providing a new strategy for developing other nickel foam-based materials for the remediation of the aqueous environment. © 2023 Elsevier B.V. |
| Keyword | Catalysts Electron transport properties Foams Free radical reactions Free radicals Manganese oxide Metal ions Nickel compounds Ecotoxicity Heterogeneous composites In-situ growth Levofloxacin Levofloxacin degradation Mn2O3/mnco2O4 Nickel foam Performance stability Peroxymonosulfate ]+ catalyst |
| Publisher | Elsevier B.V. |
| DOI | 10.1016/j.cej.2023.144629 |
| Indexed By | EI |
| Language | 英语 |
| EI Accession Number | 20232914416601 |
| EI Keywords | Rate constants |
| EI Classification Number | 531.1 Metallurgy ; 802.2 Chemical Reactions ; 803 Chemical Agents and Basic Industrial Chemicals ; 804 Chemical Products Generally |
| Original Document Type | Journal article (JA) |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | https://ir.lzu.edu.cn/handle/262010/532091 |
| Collection | 兰州大学 |
| Corresponding Author | Cheng, Xiuwen |
| Affiliation | 1.College of Chemistry and Environmental Science, Xinjiang Laboratory of Phase Transitions and Microstructures of Condensed Matter Physics, Yili Normal University, Yining; 835000, China; 2.Key Laboratory for Environmental Pollution Prediction and Control, Gansu Province, College of Earth and Environmental Sciences, Lanzhou University, Lanzhou; 730000, China |
| First Author Affilication | Lanzhou University |
| Corresponding Author Affilication | Lanzhou University |
| Recommended Citation GB/T 7714 | Song, Lixian,Cheng, Xiuwen,Yang, Ying,et al. In-situ growth of Mn2O3/MnCo2O4 on 3D nickel foam as a novel heterogeneous composites peroxymonosulfate activator for the degradation of levofloxacin: Performance, stability and mechanism[J]. CHEMICAL ENGINEERING JOURNAL,2023,471. |
| APA | Song, Lixian.,Cheng, Xiuwen.,Yang, Ying.,Hou, Yilong.,Gan, Xinrui.,...&Shang, Jiangwei.(2023).In-situ growth of Mn2O3/MnCo2O4 on 3D nickel foam as a novel heterogeneous composites peroxymonosulfate activator for the degradation of levofloxacin: Performance, stability and mechanism.CHEMICAL ENGINEERING JOURNAL,471. |
| MLA | Song, Lixian,et al."In-situ growth of Mn2O3/MnCo2O4 on 3D nickel foam as a novel heterogeneous composites peroxymonosulfate activator for the degradation of levofloxacin: Performance, stability and mechanism".CHEMICAL ENGINEERING JOURNAL 471(2023). |
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