| High dispersion Pd nanoclusters modified sulfur-rich vacancies ZnIn2S4 for high-performance hydrogen evolution | |
| Wang, Di1; Yang, Hongcen2; Tian, Shuhao2; Liu, Guo3; Wang, Ying2; Sun, Xiao2; Wang, Zhixia2; Hou, Juan1; Ma, Fei3; Peng, Shanglong1,2 | |
| 2023-11-30 | |
| Online publication date | 2023-07 |
| Source Publication | APPLIED SURFACE SCIENCE Impact Factor & Quartile |
| ISSN | 0169-4332 |
| Volume | 638 |
| page numbers | 9 |
| Abstract | Hydrogen energy is regarded as the clean energy alternative for fossil energy. Hydrogen evolution reaction (HER) is a sustainable way for the production of hydrogen energy. However, commercial platinum (Pt) catalysts for HER are expensive and scarce, which will not fully meet the demand of the future market. Therefore, scientists have been actively exploring alternatives to Pt-based catalysts. Studies have shown that palladium (Pd) and Pt have similar catalytic activity in HER. Small molecular Pd nanoclusters can be used as a perfect HER activity center. Herein, anchoring of Pd nanoclusters (Pd NCs) on sulfur-vacancy-enriched ZnIn2S4 nanosheets (Pd/ZIS-T) has been successfully achieved. The zeta potential value for ZnIn2S4 is −59.9 mV, indicating that the surface of ZnIn2S4 is abundant negatively charged in deionized water, thus providing plentiful anchoring sites to absorb Pd2+. The results show that the synergistic effect of Pd NCs and sulfur vacancies will endow the obtained catalyst with excellent electrocatalytic activity and stability. It also managed to reducing costs by reducing noble metal content. In particular, the Pd/ZIS-T electrocatalyst with excellent performance delivered low overpotential of 25 mV at 10 mA cm−2 and small Tafel slope of 33 mV dec-1 in acidic electrolyte. © 2023 Elsevier B.V. |
| Keyword | Catalyst activity Deionized water Electrocatalysts Electrolytes Hydrogen production Indium compounds Nanoclusters Palladium Sulfur Acidic Anchorings High dispersion Hydrogen Energy Hydrogen evolution reactions Hydrogen-evolution Palladium nanoclusters Performance Sulfur vacancies Surf vacancy |
| Publisher | Elsevier B.V. |
| DOI | 10.1016/j.apsusc.2023.157926 |
| Indexed By | EI ; SCIE |
| Language | 英语 |
| WOS Research Area | Chemistry ; Materials Science ; Physics |
| WOS Subject | Chemistry, Physical ; Materials Science, Coatings & Films ; Physics, Applied ; Physics, Condensed Matter |
| WOS ID | WOS:001050614400001 |
| EI Accession Number | 20233014447870 |
| EI Keywords | Zinc compounds |
| EI Classification Number | 445.1 Water Treatment Techniques ; 522 Gas Fuels ; 547.1 Precious Metals ; 702 Electric Batteries and Fuel Cells ; 761 Nanotechnology ; 803 Chemical Agents and Basic Industrial Chemicals ; 804 Chemical Products Generally ; 933 Solid State Physics |
| Original Document Type | Journal article (JA) |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | https://ir.lzu.edu.cn/handle/262010/532116 |
| Collection | 兰州大学 |
| Corresponding Author | Hou, Juan; Peng, Shanglong |
| Affiliation | 1.College of Sciences/Xinjiang Production & Construction Corps Key Laboratory of Advanced Energy Storage Materials and Technology, Shihezi University, Shihezi; 832000, China; 2.School of Materials and Energy, Lanzhou University, Lanzhou; 730000, China; 3.School of Physical Science and Technology, Lanzhou University, Lanzhou; 730000, China |
| Corresponding Author Affilication | Lanzhou University |
| Recommended Citation GB/T 7714 | Wang, Di,Yang, Hongcen,Tian, Shuhao,et al. High dispersion Pd nanoclusters modified sulfur-rich vacancies ZnIn2S4 for high-performance hydrogen evolution[J]. APPLIED SURFACE SCIENCE,2023,638. |
| APA | Wang, Di.,Yang, Hongcen.,Tian, Shuhao.,Liu, Guo.,Wang, Ying.,...&Peng, Shanglong.(2023).High dispersion Pd nanoclusters modified sulfur-rich vacancies ZnIn2S4 for high-performance hydrogen evolution.APPLIED SURFACE SCIENCE,638. |
| MLA | Wang, Di,et al."High dispersion Pd nanoclusters modified sulfur-rich vacancies ZnIn2S4 for high-performance hydrogen evolution".APPLIED SURFACE SCIENCE 638(2023). |
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