| Mesoporous Mixed-Metal-Organic Framework Incorporating a [Ru(Phen)3]2+ Photosensitizer for Highly Efficient Aerobic Photocatalytic Oxidative Coupling of Amines | |
Bai, Dongjie1; Qiu, Jinlin1; Li, Jingzhe1; Zhou, Shengbin1; Cui, Xiang2; Tang, XL(唐晓亮)1,2 ; Tang, Y(唐瑜)1; Liu, WS(刘伟生)1,2; Chen, Banglin3 | |
| 2023-06-28 | |
| Online publication date | 2023-06 |
| Source Publication | ACS Applied Materials & Interfaces Impact Factor & Quartile |
| ISSN | 1944-8244 |
| Volume | 15Issue:25Pages:30320-30331 |
| page numbers | 12 |
| Abstract | [Ru(Phen)3]2+ (phen = phenanthroline) as a very classical photosensitizer possesses strong absorption in the visible range and facilitates photoinduced electron transfer, which plays a vital role in regulating photochemical reactions. However, it remains a significant challenge to utilize more adequately and exploit more efficiently the ruthenium-based materials due to the uniqueness, scarcity, and nonrenewal of the noble metal. Here, we integrate the intrinsic advantages of the ruthenium-based photosensitizer and mesoporous metal-organic frameworks (meso-MOFs) into a [Ru(Phen)3]2+ photosensitizer-embedded heterometallic Ni(II)/Ru(II) meso-MOF (LTG-NiRu) via the metalloligand approach. LTG-NiRu, with an extremely robust framework and a large one-dimensional (1D) channel, not only makes ruthenium photosensitizer units anchored in the inner wall of meso-MOF tubes to circumvent the problem of product/catalyst separation and recycling of catalysts in heterogeneous systems but also exhibits exceptional activities for the aerobic photocatalytic oxidative coupling of amine derivatives as a general photocatalyst. The conversion of the light-induced oxidative coupling reaction for various benzylamines is ∼100% in 1 h, and more than 20 chemical products generated by photocatalytic oxidative cycloaddition of N-substituted maleimides and N,N-dimethylaniline can be synthesized easily in the presence of LTG-NiRu upon visible light irradiation. Moreover, recycling experiments demonstrate that LTG-NiRu is an excellent heterogeneous photocatalyst with high stability and excellent reusability. LTG-NiRu represents a great potential photosensitizer-based meso-MOF platform with an efficient aerobic photocatalytic oxidation function that is convenient for gram-scale synthesis. © 2023 American Chemical Society |
| Keyword | Amines Catalyst activity Chemical bonds Nickel compounds Organic polymers Organometallics Photocatalytic activity Photosensitizers Recycling Reusability Ruthenium Gram-scale synthesis Mesoporous Mesoporous metal Metalorganic frameworks (MOFs) Mixed-metals Oxidative couplings Photo-catalytic Photosensitiser Photosensitizing MOF Ru(phen) |
| Publisher | American Chemical Society |
| DOI | 10.1021/acsami.3c05397 |
| Indexed By | EI ; SCIE |
| Language | 英语 |
| WOS Research Area | Science & Technology - Other Topics ; Materials Science |
| WOS Subject | Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
| WOS ID | WOS:001006551000001 |
| EI Accession Number | 20232714331368 |
| EI Keywords | Mesoporous materials |
| EI Classification Number | 452.3 Industrial Wastes ; 547.1 Precious Metals ; 741.1 Light/Optics ; 801.4 Physical Chemistry ; 803 Chemical Agents and Basic Industrial Chemicals ; 804 Chemical Products Generally ; 804.1 Organic Compounds ; 815.1.1 Organic Polymers |
| Original Document Type | Journal article (JA) |
| PMID | 37312235 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | https://ir.lzu.edu.cn/handle/262010/532147 |
| Collection | 化学化工学院 |
| Corresponding Author | Tang, Xiaoliang; Chen, Banglin |
| Affiliation | 1.Frontiers Science Center for Rare Isotopes, Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou; 730000, China; 2.Academy of Plateau Science and Sustainability, People’s Government of Qinghai Province & Beijing Normal University, College of Chemistry and Chemical Engineering, Qinghai Normal University, Xining; 810016, China; 3.Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry & Materials Science, Fujian Normal University, Fuzhou; 350007, China |
| First Author Affilication | College of Chemistry and Chemical Engineering |
| Corresponding Author Affilication | College of Chemistry and Chemical Engineering |
| Recommended Citation GB/T 7714 | Bai, Dongjie,Qiu, Jinlin,Li, Jingzhe,et al. Mesoporous Mixed-Metal-Organic Framework Incorporating a [Ru(Phen)3]2+ Photosensitizer for Highly Efficient Aerobic Photocatalytic Oxidative Coupling of Amines[J]. ACS Applied Materials & Interfaces,2023,15(25):30320-30331. |
| APA | Bai, Dongjie.,Qiu, Jinlin.,Li, Jingzhe.,Zhou, Shengbin.,Cui, Xiang.,...&Chen, Banglin.(2023).Mesoporous Mixed-Metal-Organic Framework Incorporating a [Ru(Phen)3]2+ Photosensitizer for Highly Efficient Aerobic Photocatalytic Oxidative Coupling of Amines.ACS Applied Materials & Interfaces,15(25),30320-30331. |
| MLA | Bai, Dongjie,et al."Mesoporous Mixed-Metal-Organic Framework Incorporating a [Ru(Phen)3]2+ Photosensitizer for Highly Efficient Aerobic Photocatalytic Oxidative Coupling of Amines".ACS Applied Materials & Interfaces 15.25(2023):30320-30331. |
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