|Highly efficient and selective hydrodeoxygenation of guaiacol to cyclohexanol over a rod-like CoNi-C catalyst|
|Chen, Jing; Ma, Zongyan; Qin, Jiaheng; Chen, Ming; Dong, Linkun; Mao, Weiwen; Zhou, Xueqi; Long, Y(龙雨); Ma, JT(马建泰)|
|Online publication date||2023-07
Impact Factor & Quartile|
|Abstract||Selective hydrodeoxygenation (HDO) of guaiacol is a green and sustainable method to produce cyclohexanol. However, developing an economically efficient and highly selective non-precious metal catalyst for the HDO reaction remains a significant challenge. Here, we synthesized rod-like CoNi alloy catalysts via calcination a precursor of CoNi-BTC metal–organic framework (MOF). And a selectivity up to 94.9% can be achieved for cyclohexanol under mild reaction conditions. According to the analysis of characterization, the specific surface area and pore size had a dual impact on the catalyst activity calcinated at different temperatures. The synergistic effect of the CoNi alloy also led to an enhanced hydrogen adsorption capability of the catalyst, resulting in a significant enhancement in catalytic activity compared to the monometallic catalyst. This article provides a reference for the rational design of alloy MOF materials for catalyzing high-performance HDO of guaiacol. © 2023 Elsevier Ltd|
Coni alloy catalyst
Metalorganic frameworks (MOFs)
Non-precious metal catalysts
|WOS Research Area||Energy & Fuels
|WOS Subject||Energy & Fuels
; Engineering, Chemical
|EI Accession Number||20232914418716
|EI Keywords||Catalyst activity
|EI Classification Number||549.3 Nonferrous Metals and Alloys excluding Alkali and Alkaline Earth Metals
; 802.3 Chemical Operations
; 803 Chemical Agents and Basic Industrial Chemicals
; 804 Chemical Products Generally
; 804.1 Organic Compounds
; 931.2 Physical Properties of Gases, Liquids and Solids
; 951 Materials Science
|Original Document Type||Journal article (JA)
|Corresponding Author||Long, Yu; Ma, Jiantai|
State Key Laboratory of Applied Organic Chemistry (SKLAOC), Gansu Provincial Engineering Laboratory for Chemical Catalysis, College of Chemistry and Chemical Engineering, Lanzhou University, Gansu, Lanzhou; 730000, China
|First Author Affilication||College of Chemistry and Chemical Engineering
|Corresponding Author Affilication||College of Chemistry and Chemical Engineering
Chen, Jing,Ma, Zongyan,Qin, Jiaheng,et al. Highly efficient and selective hydrodeoxygenation of guaiacol to cyclohexanol over a rod-like CoNi-C catalyst[J].
Chen, Jing.,Ma, Zongyan.,Qin, Jiaheng.,Chen, Ming.,Dong, Linkun.,...&Ma, Jiantai.(2023).Highly efficient and selective hydrodeoxygenation of guaiacol to cyclohexanol over a rod-like CoNi-C catalyst.FUEL,353.
Chen, Jing,et al."Highly efficient and selective hydrodeoxygenation of guaiacol to cyclohexanol over a rod-like CoNi-C catalyst".FUEL 353(2023).
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.