| Highly efficient and selective hydrodeoxygenation of guaiacol to cyclohexanol over a rod-like CoNi-C catalyst | |
Chen, Jing; Ma, Zongyan; Qin, Jiaheng; Chen, Ming; Dong, Linkun; Mao, Weiwen; Zhou, Xueqi; Long, Y(龙雨) ; Ma, JT(马建泰) | |
| 2023-12-01 | |
| Online publication date | 2023-07 |
| Source Publication | FUEL Impact Factor & Quartile |
| ISSN | 0016-2361 |
| Volume | 353 |
| page numbers | 9 |
| Abstract | Selective hydrodeoxygenation (HDO) of guaiacol is a green and sustainable method to produce cyclohexanol. However, developing an economically efficient and highly selective non-precious metal catalyst for the HDO reaction remains a significant challenge. Here, we synthesized rod-like CoNi alloy catalysts via calcination a precursor of CoNi-BTC metal–organic framework (MOF). And a selectivity up to 94.9% can be achieved for cyclohexanol under mild reaction conditions. According to the analysis of characterization, the specific surface area and pore size had a dual impact on the catalyst activity calcinated at different temperatures. The synergistic effect of the CoNi alloy also led to an enhanced hydrogen adsorption capability of the catalyst, resulting in a significant enhancement in catalytic activity compared to the monometallic catalyst. This article provides a reference for the rational design of alloy MOF materials for catalyzing high-performance HDO of guaiacol. © 2023 Elsevier Ltd |
| Keyword | Alcohols Binary alloys Cobalt alloys Gas adsorption Pore size Alloy catalyst Co/Ni alloy Coni alloy catalyst Cyclohexanol Guaiacol Hydrodeoxygenation Metalorganic frameworks (MOFs) Non-precious metal catalysts Synthesised ]+ catalyst |
| Publisher | Elsevier Ltd |
| DOI | 10.1016/j.fuel.2023.129216 |
| Indexed By | EI ; SCIE |
| Language | 英语 |
| WOS Research Area | Energy & Fuels ; Engineering |
| WOS Subject | Energy & Fuels ; Engineering, Chemical |
| WOS ID | WOS:001042884800001 |
| EI Accession Number | 20232914418716 |
| EI Keywords | Catalyst activity |
| EI Classification Number | 549.3 Nonferrous Metals and Alloys excluding Alkali and Alkaline Earth Metals ; 802.3 Chemical Operations ; 803 Chemical Agents and Basic Industrial Chemicals ; 804 Chemical Products Generally ; 804.1 Organic Compounds ; 931.2 Physical Properties of Gases, Liquids and Solids ; 951 Materials Science |
| Original Document Type | Journal article (JA) |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | https://ir.lzu.edu.cn/handle/262010/532333 |
| Collection | 化学化工学院 |
| Corresponding Author | Long, Yu; Ma, Jiantai |
| Affiliation | State Key Laboratory of Applied Organic Chemistry (SKLAOC), Gansu Provincial Engineering Laboratory for Chemical Catalysis, College of Chemistry and Chemical Engineering, Lanzhou University, Gansu, Lanzhou; 730000, China |
| First Author Affilication | College of Chemistry and Chemical Engineering |
| Corresponding Author Affilication | College of Chemistry and Chemical Engineering |
| Recommended Citation GB/T 7714 | Chen, Jing,Ma, Zongyan,Qin, Jiaheng,et al. Highly efficient and selective hydrodeoxygenation of guaiacol to cyclohexanol over a rod-like CoNi-C catalyst[J]. FUEL,2023,353. |
| APA | Chen, Jing.,Ma, Zongyan.,Qin, Jiaheng.,Chen, Ming.,Dong, Linkun.,...&Ma, Jiantai.(2023).Highly efficient and selective hydrodeoxygenation of guaiacol to cyclohexanol over a rod-like CoNi-C catalyst.FUEL,353. |
| MLA | Chen, Jing,et al."Highly efficient and selective hydrodeoxygenation of guaiacol to cyclohexanol over a rod-like CoNi-C catalyst".FUEL 353(2023). |
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