| Functional Construction of a Novel Lanthanide MOF for Efficient Ratio Luminescence Detection of Ethanol Vapor | |
Sun, Yiliang1; Wang, Xiaoyan1; Liu, Shiying2; Yang, Xiaoshan2; Ren, XY(任晓钰)3 ; Liu, Wei1; Liu, WS(刘伟生)2 | |
| 2024 | |
| Online publication date | 2024-05 |
| Source Publication | Advanced Optical Materials Impact Factor & Quartile Of Published Year The Latest Impact Factor & Quartile |
| ISSN | 2195-1071 |
| EISSN | 2195-1071 |
| page numbers | 9 |
| Abstract | It is necessary to develop excellent sensors for volatile organic compounds (VOCs) detection from the perspective of environmental protection and human health. Luminescent lanthanide metal-organic frameworks (MOFs) have many advantages such as porosity, luminescence, and structural controllability, making them very suitable as luminescent sensing materials. Based on a functional oriented strategy, novel Ln-MOFs are successfully constructed and their structure and properties are characterized in detail. A series of vapor luminescence sensing tests have shown that Eu/Tb doped L1-Eu0.1/Tb0.9 not only exhibits high selectivity for alcohols, especially ethanol vapor, but also has high sensitivity and extremely low detection limit (9.76 mg L−1). To the knowledge, there are no reports on ratio luminescence sensors based on Ln-MOFs for ethanol vapor, especially those with such excellent performance. Crystal structure determination demonstrates that ethanol binds to the framework through multiple hydrogen bonding interactions, altering the energy transfer efficiency between Tb3+ and Eu3+ to achieve ratio luminescence detection. In addition, L1-Eu0.1/Tb0.9 has good repeatability, the prepared thin film sensing material also demonstrates the advantages of portability and processability. This work can provide some experience for the development of VOCs sensing materials with better performance. © 2024 Wiley-VCH GmbH. |
| Keyword | Crystal structure Energy transfer Ethanol Hydrogen bonds Luminescence Metal-Organic Frameworks Volatile organic compounds Ethanol vapours Functional constructions Human health Lanthanide element Luminescence detection Luminescent sensors Metalorganic frameworks (MOFs) Performance Sensing material Structural controllability ethanol vapor lanthanide elements luminescent sensor metal-organic frameworks |
| Publisher | John Wiley and Sons Inc |
| DOI | 10.1002/adom.202400692 |
| Indexed By | EI ; SCIE |
| Language | 英语 |
| WOS Research Area | Materials Science ; Optics |
| WOS Subject | Materials Science, Multidisciplinary ; Optics |
| WOS ID | WOS:001217089100001 |
| EI Accession Number | 20241916028788 |
| EI Keywords | Rare earth elements |
| EI Classification Number | 531.1 Metallurgy ; 547.2 Rare Earth Metals ; 741.1 Light/Optics ; 801.4 Physical Chemistry ; 804.1 Organic Compounds ; 933.1.1 Crystal Lattice |
| Original Document Type | Article in Press ; Article ; Early Access |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | https://ir.lzu.edu.cn/handle/262010/592641 |
| Collection | 兰州大学 化学化工学院 核科学与技术学院 基础医学院 |
| Affiliation | 1.Frontiers Science Center for Rare Isotope, School of Nuclear Science and Technology, Institute of National Nuclear Industry, Lanzhou University, Lanzhou; 730000, China; 2.Key Laboratory of Nonferrous Metals Chemistry and Resources Utilization of Gansu Province, State Key Laboratory of Applied Organic Chemistry, Frontiers Science Center for Rare Isotope, and College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou; 730000, China; 3.Key Laboratory of Preclinical Study for New Drugs of Gansu Province, School of Basic Medical Sciences, Lanzhou University, Lanzhou; 730000, China |
| First Author Affilication | School of Nuclear Science and Technology |
| First Signature Affilication | School of Nuclear Science and Technology |
| Recommended Citation GB/T 7714 | Sun, Yiliang,Wang, Xiaoyan,Liu, Shiying,et al. Functional Construction of a Novel Lanthanide MOF for Efficient Ratio Luminescence Detection of Ethanol Vapor[J]. Advanced Optical Materials,2024. |
| APA | Sun, Yiliang.,Wang, Xiaoyan.,Liu, Shiying.,Yang, Xiaoshan.,Ren, Xiaoyu.,...&Liu, Weisheng.(2024).Functional Construction of a Novel Lanthanide MOF for Efficient Ratio Luminescence Detection of Ethanol Vapor.Advanced Optical Materials. |
| MLA | Sun, Yiliang,et al."Functional Construction of a Novel Lanthanide MOF for Efficient Ratio Luminescence Detection of Ethanol Vapor".Advanced Optical Materials (2024). |
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