| Construction of Covalent Organic Framework for Catalysis: Pd/COF-LZU1 in Suzuki-Miyaura Coupling Reaction | |
Ding, SY(丁三元) ; Gao, J; Wang, Q; Zhang, Y; Song, WG; Su, CY; Wang, W(王为); Wang, W (reprint author), Lanzhou Univ, State Key Lab Appl Organ Chem, Coll Chem & Chem Engn, Lanzhou 730000, Gansu, Peoples R China. | |
| ESI NOTE | 2017-07-19;Highly Cited Papers |
| 2011-12-14 | |
| Source Publication | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| ISSN | 0002-7863 |
| Volume | 133Issue:49 |
| Abstract | Covalent organic frameworks (COFs) are crystalline porous solids with well-defined two- or three-dimensional molecular structures. Although the structural regularity provides this new type of porous material with high potentials in catalysis, no example has been presented so far. Herein, we report the first application of a new COF material, COF-LZU1, for highly efficient catalysis. The easily prepared imine-linked COF-LZU1 possesses a two-dimensional eclipsed layered-sheet structure, making its incorporation with metal ions feasible. Via a simple post-treatment, a Pd(II)-containing COF, Pd/COF-LZU1, was accordingly synthesized, which showed excellent catalytic activity in catalyzing the Suzuki-Miyaura coupling reaction. The superior utility of Pd/COF-LZU1 in catalysis was elucidated by the broad scope of the reactants and the excellent yields (96-98%) of the reaction products, together with the high stability and easy recyclability of the catalyst. We expect that our approach will further boost research on designing and employing functional COF materials for catalysis. |
| Subject Area | Chemistry |
| Publisher | AMER CHEMICAL SOC |
| DOI | 10.1021/ja206846p |
| Publication Place | WASHINGTON |
| Indexed By | SCIE ; EI ; PubMed ; ESI |
| Language | 英语 |
| First Inst | 是 |
| Funding Project | 国家自然科学基金项目 ; 教育部科学技术研究重大项目 ; 高等学校学科创新引智计划（111计划） |
| Project Number | National Natural Science Foundation of China [20933009, 20972064] ; Chinese Ministry of Education [309028] ; 111 Project |
| WOS ID | WOS:000298719800048 |
| Funding Organization | National Natural Science Foundation of China [20933009, 20972064]; Chinese Ministry of Education [309028]; 111 Project ; NSFC ; SAFEA ; MOE |
| Subtype | Article |
| EI ID | 20115014597783 |
| PMID | 22026454 |
| Department | [Ding, San-Yuan;Gao, Jia;Wang, Qiong;Zhang, Yuan;Wang, Wei] Lanzhou Univ, State Key Lab Appl Organ Chem, Coll Chem & Chem Engn, Lanzhou 730000, Gansu, Peoples R China;[Wang, Qiong;Song, Wei-Guo] Chinese Acad Sci, Inst Chem, Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China;[Wang, Qiong;Song, Wei-Guo] Chinese Acad Sci, Beijing Natl Lab Mol Sci BNLMS, Beijing 100190, Peoples R China;[Su, Cheng-Yong] Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Guangdong, Peoples R China...更多 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | https://ir.lzu.edu.cn/handle/262010/76261 |
| Collection | 化学化工学院 |
| Corresponding Author | Wang, W (reprint author), Lanzhou Univ, State Key Lab Appl Organ Chem, Coll Chem & Chem Engn, Lanzhou 730000, Gansu, Peoples R China. |
| Recommended Citation GB/T 7714 | Ding, SY,Gao, J,Wang, Q,et al. Construction of Covalent Organic Framework for Catalysis: Pd/COF-LZU1 in Suzuki-Miyaura Coupling Reaction[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2011,133(49). |
| APA | Ding, SY.,Gao, J.,Wang, Q.,Zhang, Y.,Song, WG.,...&Wang, W .(2011).Construction of Covalent Organic Framework for Catalysis: Pd/COF-LZU1 in Suzuki-Miyaura Coupling Reaction.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,133(49). |
| MLA | Ding, SY,et al."Construction of Covalent Organic Framework for Catalysis: Pd/COF-LZU1 in Suzuki-Miyaura Coupling Reaction".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 133.49(2011). |
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| 000298719800048.pdf（2635KB） | 开放获取 | CC BY-NC-ND | View Application Full Text | ||
