Direct Sp(3) alpha-C-H activation and functionalization of alcohol and ether

doi:10.1039/c0cs00063a

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	Direct Sp(3) alpha-C-H activation and functionalization of alcohol and ether
	Zhang, SY; Zhang, FM(张辅民); Tu, YQ(涂永强); Tu, YQ (reprint author), Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China.
ESI NOTE	2017-07-19;Highly Cited Papers
	2011
Source Publication	CHEMICAL SOCIETY REVIEWS
ISSN	0306-0012
Volume	40 Issue:4
Abstract	Seven kinds of sp(3) alpha-C-H activation/C-C formation reactions of alcohols and ethers have been reviewed in this tutorial review, from the viewpoint of both methodology and synthetic application, towards the efficiency, chemo-, regio- and stereoselectivity, catalytic system, substrate scope and mechanistic study. Section 2 describes radical-mediated alpha-C-H activation and addition/elimination of ethers with unsaturated (C=C and C C) species. Sections 3-8 discuss the alpha-C-H activation and additions of alcohols and/or ethers with unsaturated (C=C, C C, C=O and C=N) compounds, which involve the key processes of radical mediation, carbenoid insertion, 1,5-H-migration, oxidative dehydrogenation coupling, transfer hydrogenative coupling, and metal-mediated C=C insertion into the C-H bond.
Subject Area	Chemistry
Publisher	ROYAL SOC CHEMISTRY
DOI	10.1039/c0cs00063a
Publication Place	CAMBRIDGE
Indexed By	SCIE ; PubMed ; ESI
Language	英语
First Inst	是
Funding Project	国家自然科学基金项目 ; 国家重点基础研究发展计划以及国家重大科学研究计划（973计划）
Project Number	NSFC [20732002, 20921120404, 20972059, 21072085] ; MOE ; MOST [2010CB833203]
WOS ID	WOS:000288609400009
Funding Organization	NSFC [20732002, 20921120404, 20972059, 21072085]; MOE; MOST [2010CB833203] ; NSFC ; MOST ; MOE
Subtype	Review
PMID	21286642
Department	[Tu, Yong-Qiang] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China; Lanzhou Univ, Dept Chem, Lanzhou 730000, Peoples R China
Citation statistics	Cited Times:394[WOS] [WOS Record] [Related Records in WOS]
Document Type	期刊论文
Identifier	https://ir.lzu.edu.cn/handle/262010/76590
Collection	化学化工学院
Corresponding Author	Tu, YQ (reprint author), Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China.
Recommended Citation GB/T 7714	Zhang, SY,Zhang, FM,Tu, YQ,et al. Direct Sp(3) alpha-C-H activation and functionalization of alcohol and ether[J]. CHEMICAL SOCIETY REVIEWS,2011,40(4).
APA	Zhang, SY,Zhang, FM,Tu, YQ,&Tu, YQ .(2011).Direct Sp(3) alpha-C-H activation and functionalization of alcohol and ether.CHEMICAL SOCIETY REVIEWS,40(4).
MLA	Zhang, SY,et al."Direct Sp(3) alpha-C-H activation and functionalization of alcohol and ether".CHEMICAL SOCIETY REVIEWS 40.4(2011).

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