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Asymmetric Intramolecular Hydroalkylation of Internal Olefin with Cycloalkanone to Directly Access Polycyclic Systems
期刊论文
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2023, 卷号: 62, 期号: 39
Authors:
Wang, Ai-Fang
;
Tian, Jin-Miao
;
Zhao, Xiao-Jing
;
Li, Zi-Hao
;
Zhang, Ye
;
Lu, Ka
;
Wang, Hong
;
Zhang, Shu-Yu
;
Tu, Yong-Qiang
;
Ding, Tong-Mei
...
Wang, Ai-Fang
;
Tian, Jin-Miao
;
Zhao, Xiao-Jing
;
Li, Zi-Hao
;
Zhang, Ye
;
Lu, Ka
;
Wang, Hong
;
Zhang, Shu-Yu
;
Tu, Yong-Qiang
;
Ding, Tong-Mei
;
Xie, Yu-Yang
Favorite
  |  
  
Submit date:2023/11/28
Cooperative Catalysis
Hydroalkylation
Polycyclic Systems
SPD-NH2
Unactivated Olefins
NiH-Catalyzed Regio- and Enantioselective Hydroalkylation for the Synthesis of β- or ?-Branched Chiral Aromatic N-Heterocycles
期刊论文
Journal of the American Chemical Society, 2023, 卷号: 145, 期号: 40, 页码: 22122-22134
Authors:
Yang, Ju-Song
;
Lu, Ka
;
Li, Chen-Xiao
;
Zhao, Zu-Hang
;
Zhang, Fu-Min
;
Zhang, Xiao-Ming
;
Tu, Yong-Qiang
Favorite
  |  
  
Submit date:2023/11/28
Aromatic and olefinic C-H alkenylation by catalysis with spirocyclic NHC Ru(IV) pincer complex
期刊论文
Science China-Chemistry, 2023, 卷号: 66, 期号: 10, 页码: 2791-2796
Authors:
Cai, Heng
;
Tu, Yong-Qiang
;
Lu, Ka
;
Chen, Qi-Long
;
Zhang, Fu-Min
;
Zhang, Xiao-Ming
;
Pan, Yuan-Jiang
;
Yan, Zhi-Bo
Favorite
  |  
  
Submit date:2023/05/25
Aromatic compounds
Aromatization
Catalysis
Electron transitions
Olefins
Ruthenium compounds
Transition metals
Alkenyl
C-H alkenylation
Electron transfer pathways
N-heterocyclic carbenes
Single electron transfer
Single electron transfer pathway
Spirocyclic N-heterocyclic carbene-ru pincer catalyst
Transition metal catalysis
Triflates
Unactivated alkenyl bromide and triflate
]+ catalyst
Catalytic Enantioselective Steglich-Type Rearrangement of Enol Lactones: Asymmetric Synthesis of Spirocyclic 1,3-Diketones
期刊论文
JOURNAL OF ORGANIC CHEMISTRY, 2022, 卷号: 87, 期号: 22, 页码: 15031-15041
Authors:
Zhang, Xiao-Yan
;
Lu, Ka
;
Guo, Bao-Kuan
;
Shao, Ya-Ping
;
Wang, Hong
;
Zhang, Fu-Min
;
Tu, Yong-Qiang
;
Zhang, Xiao-Ming
Favorite
  |  
  
Submit date:2023/01/03
Enantioselectivity
Ketones
Acyl transfer reaction
Asymmetric synthesis
Diketones
Enantioselective
Enol lactones
Iminium cation
Isothiourea
Mechanistic studies
Synthetic approach
β-Diketones
Catalytic Enantioselective Steglich-Type Rearrangement of Enol Lactones: Asymmetric Synthesis of Spirocyclic 1,3-Diketones
期刊论文
JOURNAL OF ORGANIC CHEMISTRY, 2022
Authors:
Zhang, Xiao-Yan
;
Lu, Ka
;
Guo, Bao-Kuan
;
Shao, Ya-Ping
;
Wang, Hong
;
Zhang, Fu-Min
;
Tu, Yong-Qiang
;
Zhang, Xiao-Ming
Favorite
  |  
  
Submit date:2023/01/03
Facile Benzylic Alkylation of Arenes with Alcohols by Catalysis with Spirocyclic NHC IrIII Pincer Complex
期刊论文
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 卷号: 61, 期号: 38
Authors:
Dai, Kun-Long
;
Chen, Qi-Long
;
Xie, Wen-Ping
;
Lu, Ka
;
Yan, Zhi-Bo
;
Peng, Meng
;
Li, Chang-Kun
;
Tu, Yong-Qiang
;
Ding, Tong-Mei
Favorite
  |  
  
Submit date:2022/11/08
Alkylation
Catalysis
Density functional theory
Functional materials
Hydrogen
Iridium compounds
Polycyclic aromatic hydrocarbons
Synthesis (chemical)
Benzylic
Borrowing hydrogens
C-alkylation
Hemilabile intermediate
Iridium catalysis
Pincer complexes
Primary alcohols
Secondary alcohols
Synthetic methods
]+ catalyst
Facile Benzylic Alkylation of Arenes with Alcohols by Catalysis with Spirocyclic NHC Ir-III Pincer Complex
期刊论文
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 卷号: 61, 期号: 38
Authors:
Dai, Kun-Long
;
Chen, Qi-Long
;
Xie, Wen-Ping
;
Lu, Ka
;
Yan, Zhi-Bo
;
Peng, Meng
;
Li, Chang-Kun
;
Tu, Yong-Qiang
;
Ding, Tong-Mei
Favorite
  |  
  
Submit date:2022/11/09
Alkylation
Borrowing Hydrogen
Hemilabile Intermediate
Iridium Catalysis
Synthetic Methods
Organocatalytic synthesis of chiral allene catalyzed by chiral phosphoric acid via asymmetric 1,8-addition of indole imine methide: Mechanism and origin of enantioselectivity
期刊论文
Molecular Catalysis, 2022, 卷号: 530
Authors:
Liang, Peng -Yu
;
Shi, Shaoting
;
Xu, Xin-Xin
;
Zhang, Hai-Rong
;
Che, Zheng
;
Lu, Ka
;
Yan, Chao-Xian
;
Jin, Neng-Zhi
;
Zhou, Pan-Pan
Favorite
  |  
  
Submit date:2022/11/09
Chiral phosphoric acid
Hydrogen bond
Enantioselectivity
Chiral allene
Organocatalytic reaction
Chiral 1,2,3-Triazolium Salt Catalyzed Asymmetric Mono- and Dialkylation of 2,5-Diketopiperazines with the Construction of Tetrasubstituted Carbon Centers
期刊论文
Angewandte Chemie - International Edition, 2022, 卷号: 61, 期号: 9
Authors:
Yang, Ju-Song
;
Lu, Ka
;
Li, Chen-Xiao
;
Zhao, Zu-Hang
;
Zhang, Xiao-Ming
;
Zhang, Fu-Min
;
Tu, Yong-Qiang
Favorite
  |  
  
Submit date:2022/03/18
Amides
Carbon
Catalysis
Carbon stereocenters
Dialkylation
Diastereo- and enantioselectivity
Diketopiperazines
Functionalized
Higher yield
Monoalkylation
Organocatalysts
Reaction mechanism
Synthetic approach
Chiral 1,2,3-Triazolium Salt Catalyzed Asymmetric Mono- and Dialkylation of 2,5-Diketopiperazines with the Construction of Tetrasubstituted Carbon Centers
期刊论文
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 卷号: 61, 期号: 9
Authors:
Yang, Ju-Song
;
Lu, Ka
;
Li, Chen-Xiao
;
Zhao, Zu-Hang
;
Zhang, Xiao-Ming
;
Zhang, Fu-Min
;
Tu, Yong-Qiang
Favorite
  |  
  
Submit date:2022/04/20
1
2
3-Triazolium Salts
2
5-Diketopiperazines
Asymmetric Catalysis
Dialkylation
Phase-Transfer Catalysis